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Analytical Chemistry

Analytical chemistry is the subject for the method and basic principle of studying and identifying of the composition, status, structure of matter as well as determination of related content. It is an important branch of chemistry subject. Analytical chemistry plays an important role in not only its own development but also in various fields related to the chemistry. We can say that all the practice of any human activity involving chemical phenomena is inseparable from analytical chemistry. Now, people have developed various kinds of different analytical methods, which can be classified based on an analysis task, analysis object, the basis of the analysis, requirement of the analysis and sample dosage.

According to the analysis tasks, it can be divided into qualitative analysis, quantitative analysis and structural analysis. Task of qualitative analysis is to identify the elements, radicals, functional groups or compounds that constituting the substances; the task of the quantitative analysis is to determine the content of the related components in the sample; the task of structural analysis is to study the molecular structure or crystal structure of the material.

(1) According to the analysis objects, it can be divided into organic and inorganic analysis; the object for the inorganic analysis is inorganic substance; the object of organic analysis is organic substance. In the inorganic analysis, it is generally required to determine what elements, ions, radicals or compounds that constitutes the sample and measure the percentage of each component; and sometimes it is also necessary for determination of the crystal structure; in the organic analysis, it not only requires the identification of the constituent elements, but also, more importantly, should do the structure analysis and functional group analysis.
(2) According to whether the analysis is based on the physical properties or chemical properties of the substance, it can be divided into instrumental analysis and chemical analysis. Depending on the specific requirements, it can be divided into routine analysis, rapid analysis and arbitration Analysis. Routine analysis refers to the general daily laboratory production analysis, also known as conventional analysis; rapid analysis is a kind of routine analysis and is mainly applied to the control of the production process, demanding the report of the results in the shortest possible time with the error generally being allowed to be greater; arbitration analysis is needed when there is controversy in the analysis results from different institute, demanding related department to conduct accurate analysis using specific method in order to determine the accuracy of the results of the original analysis.
(3) According to the amount of the sample, it can be generally divided into constant (> 0.1g), semi-micro (0.01 ~ 0.1g) and trace (1 ~ 10mg) analysis.
(4) In the inorganic qualitative chemical analysis, people generally apply semi-micro method while people generally apply constant analysis in the quantitative chemical analysis. According to the relative amounts of the analyzed components contained in the sample, it is also roughly divided into constant component analysis (> 1%), minor component analysis (0.01 to 1%) and trace components analysis (<0.01%). For the analysis of some trace amount of components contained in some kinds of complicated mixture and some substances, it is necessary to perform separation and enrichment. This produces a series of separation techniques, such as extraction, distillation, ion exchange, chromatography, sedimentation and flotation separation, these chemical separation techniques are an integral part of the analysis.

Environmental Analytical Chemistry
Environmental Analytical Chemistry is briefly referred to environmental analysis. It is a kind of subject to study the types, components of pollutants in the environment as well as how to perform qualitative and quantitative analysis on the chemical contaminants in the environment. It is a branch of environmental chemistry.

Environmental analytical chemistry emerged, developed and improved during the process of solving environmental problems. In 1950s, the public nuisance disease occurred in Japan had alerted the whole world. In order to find the cause of public nuisance disease, after experiencing as long as 11 years, later, the chemists of environmental analysis had applied light spectrum and identified that the river in Itai-itai disease area contained harmful elements such as lead, cadmium, arsenic and so on. Further by means of tracking element analysis of the soil and food in the disease area, people had found high lead and cadmium content. Later, people had further conducted spectral quantitative analysis on the body and bone of the patients in the disease area and found that the bone ashes contained alarmingly high content of zinc, lead and cadmium. To determine the causative agent, people further incorporated zinc, lead and cadmium into the food for feeding animals and conduct trace elemental analysis for animals and confirmed the serious harm of cadmium on the bone, revealing the cause of the Itai-itai disease. The development of modern science, especially the development of modern chemistry, physics, mathematics, electronics, biology, as well as the emergence of accurate, reliable, sensitive, selective, rapid, simple environmental pollution analysis technology and automation equipment, has been resulting in the maturation of environmental analytical chemistry. Environmental analytical chemistry now has penetrated into all areas of the entire environmental science subject. It is the most effective means of access to environmental information quality.
The objects of the environmental analytical chemistry research are quite complicated, including air, water, soil, sediment, minerals, waste, animals, plants, food, and human tissue. The content of chemical elements or compound to be determined in the environmental analytic chemistry is very low, with the absolute content being within the level of 10-6 to 10-12 grams.


The analysis technology in the environmental analytical chemistry is developing towards the direction of continuous automation, computerization and joint combination of various methods and instruments. Currently applied automatic analysis methods include colorimetric analysis, ion selective electrode, x-ray fluorescence spectroscopy, atomic absorption spectroscopy, polarography, gas chromatography, liquid chromatography and flow injection analysis. Laser, as the light source of analytical chemistry technique, has also been applied. Since the laser analysis has properties of high resolution, high sensitivity, long-range and short-term, the laser technology will play a pivotal role in the development of environmental analytical chemistry.

With the deepened development of environmental science, environmental analytical chemistry is often demanded for trace levels and ultra-trace-level detection and analysis, therefore, high sensitivity. Thus study of analysis methods of high sensitivity, good selectivity, rapid trace and ultra trace will become the major development direction for environmental analysis in the near future.

Qualitative Analysis of Chemistry
Qualitative analytic chemistry is the subject to identify the chemical elements and atoms groups contained in the sample. It is a branch subject of the analysis chemistry. Its purpose is to ascertain the chemical composition of the research object (specimen).
The major research content of the qualitative analytic chemistry includes:

1 the tested samples were analyzed separately. Namely take part of the sample and use exclusive reaction to detect a desire detection component.
2 systematic analysis of the samples. This means successively apply a few selective reactions for gradual separation of the ions followed by separation of each group until separating to only one substance and finally apply confirming reaction to ascertain the existence of this substance. The most famous cation system analysis method is H2S system. In recent years, due to the use of advanced equipment, qualitative analysis has also rapidly developed together with multivariate analysis and has also become an important direction for analytical chemistry.

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Structure Chemical Name CAS MF
2,3,3',4,5,5'-HEXACHLOROBIPHENYL 2,3,3',4,5,5'-HEXACHLOROBIPHENYL 39635-35-3 C12H4Cl6
2,2',3,3',4',5,5',6-OCTACHLOROBIPHENYL 2,2',3,3',4',5,5',6-OCTACHLOROBIPHENYL 52663-75-9 C12H2Cl8
KINOPRENE KINOPRENE 42588-37-4 C18H28O2
N,O-BIS(TERT-BUTYLDIMETHYLSILYL)ACETAMIDE N,O-BIS(TERT-BUTYLDIMETHYLSILYL)ACETAMIDE 82112-21-8 C14H33NOSi2
2,2',3,4,5'-PENTACHLOROBIPHENYL 2,2',3,4,5'-PENTACHLOROBIPHENYL 38380-02-8 C12H5Cl5
1,12-OCTADECANEDIOL 1,12-OCTADECANEDIOL 2726-73-0 C18H38O2
AMBERLITE(R) IRC-748 AMBERLITE(R) IRC-748 79620-28-3
HEPTACOSANOIC ACID METHYL ESTER HEPTACOSANOIC ACID METHYL ESTER 55682-91-2 C28H56O2
2,2',3,4,4',5',6-HEPTACHLOROBIPHENYL 2,2',3,4,4',5',6-HEPTACHLOROBIPHENYL 52663-69-1 C12H3Cl7
Ziprasidone mesilate Ziprasidone mesilate 199191-69-0 C22H31ClN4O7S2
CYPROFURAM CYPROFURAM 69581-33-5 C14H14ClNO3
NYLIDRIN HYDROCHLORIDE NYLIDRIN HYDROCHLORIDE 849-55-8 C19H26ClNO2
HUMAN FACTOR IX HUMAN FACTOR IX 9001-28-9
ROBINETINIDIN CHLORIDE ROBINETINIDIN CHLORIDE 3020-09-5 C15H11ClO6
2,2',4,4',5-PENTACHLOROBIPHENYL 2,2',4,4',5-PENTACHLOROBIPHENYL 38380-01-7 C12H5Cl5
HALOFENOZIDE HALOFENOZIDE 112226-61-6 C18H19ClN2O2
OSELTAMIVIR ACID OSELTAMIVIR ACID 187227-45-8 C14H24N2O4
AROCLOR 1254, 1X1ML, ISO, 1000UG/ML AROCLOR 1254, 1X1ML, ISO, 1000UG/ML 11097-69-1 C12H5Cl5
DIAZINON (DIETHYL-D10) DIAZINON (DIETHYL-D10) 100155-47-3 C12H11D10N2O3PS
(R,S)-N-NITROSOANABASINE (R,S)-N-NITROSOANABASINE 37620-20-5 C10H13N3O
N-METHYLBIS(HEPTAFLUOROBUTYRAMIDE) N-METHYLBIS(HEPTAFLUOROBUTYRAMIDE) 73980-71-9 C9H3F14NO2
THIOFANOX THIOFANOX 39196-18-4 C9H18N2O2S
DEAE Sephadex A-25 DEAE Sephadex A-25 12609-80-2
EMEDASTINE FUMARATE EMEDASTINE FUMARATE 87233-62-3 C25H34N4O9
HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE 121-82-4 C3H6N6O6
OLEIC ACID OLEYL ESTER OLEIC ACID OLEYL ESTER 3687-45-4 C36H68O2
D-SACCHARIC ACID CALCIUM SALT TETRAHYDRATE D-SACCHARIC ACID CALCIUM SALT TETRAHYDRATE 5793-89-5 C6H14CaO9
β-Elemonic Acid β-Elemonic Acid 28282-25-9 C30H46O3
GLYCIDAMIDE GLYCIDAMIDE 5694-00-8 C3H5NO2
11TR-EICOSENOIC ACID 11TR-EICOSENOIC ACID 62322-84-3 C20H38O2
Hydroxymetronidazole Hydroxymetronidazole 4812-40-2 C6H9N3O4
BUTTPARK 32\09-93 BUTTPARK 32\09-93 111562-32-4 C9H9N3
UNIVERSAL INDICATOR UNIVERSAL INDICATOR
Benzarone Benzarone 1477-19-6 C17H14O3
1-(8-Bromo-2,3,6,7-tetrahydrobenzodifuran-4-yl)-2-aminoethane hydrochloride 1-(8-Bromo-2,3,6,7-tetrahydrobenzodifuran-4-yl)-2-aminoethane hydrochloride 178557-21-6 C12H15BrClNO2
Zilpaterol hydrochloride Zilpaterol hydrochloride 119520-06-8 C14H20ClN3O2
Estradiol hemihydrate Estradiol hemihydrate 35380-71-3 C18H24O2.H2O
Firocoxib Firocoxib 189954-96-9 C17H20O5S
PantoprazoleSodiumSesquihydrate PantoprazoleSodiumSesquihydrate 164579-32-2 C16H18F2N3NaO5S
PROTEIN A RESIN PROTEIN A RESIN
FISETINIDIN CHLORIDE FISETINIDIN CHLORIDE 2948-76-7 C15H11ClO5
ARISTOLOCHIC ACID SODIUM SALT ARISTOLOCHIC ACID SODIUM SALT 10190-99-5 C17H12NNaO7
MEFEXAMIDE HYDROCHLORIDE MEFEXAMIDE HYDROCHLORIDE 1227-61-8 C15H24N2O3
Ticarcillin sodium Ticarcillin sodium 74682-62-5 C15H14N2Na2O6S2
NALPHA-(5-FLUORO-2,4-DINITROPHENYL)-D-LEUCINAMIDE NALPHA-(5-FLUORO-2,4-DINITROPHENYL)-D-LEUCINAMIDE 178065-30-0 C12H15FN4O5
PRIDINOL METHANESULFONATE SALT PRIDINOL METHANESULFONATE SALT 6856-31-1 C21H29NO4S
(3-BROMO-2,4,6-TRIMETHYLPHENYLCARBAMOYL)METHYLIMINODIACETIC ACID (3-BROMO-2,4,6-TRIMETHYLPHENYLCARBAMOYL)METHYLIMINODIACETIC ACID 78266-06-5 C15H19BrN2O5
4-ACETYLAMINO-N-(5-METHYL-3-ISOXAZOLYL)BENZENESULFONAMIDE 4-ACETYLAMINO-N-(5-METHYL-3-ISOXAZOLYL)BENZENESULFONAMIDE 21312-10-7 C12H13N3O4S
RANITIDINE IMPURITY C RANITIDINE IMPURITY C 73851-70-4 C13H22N4O4S
4,4'-Ethylidenebisphenol 4,4'-Ethylidenebisphenol 2081-08-5 C14H14O2
Hydromorphone hydrochloride Hydromorphone hydrochloride 71-68-1 C17H20ClNO3
2,3',4,4',5-PENTACHLOROBIPHENYL 2,3',4,4',5-PENTACHLOROBIPHENYL 31508-00-6 C12H5Cl5
TIN(II) STEARATE TIN(II) STEARATE 6994-59-8 C36H70O4Sn
OLIGO(DT)-CELLULOSE OLIGO(DT)-CELLULOSE
NBD-CO-HZ NBD-CO-HZ 221263-97-4 C9H10N6O4
Todralazine hydrochloride Todralazine hydrochloride 3778-76-5 C11H13ClN4O2
BENZYL ISOPROPENYL ETHER BENZYL ISOPROPENYL ETHER 32783-20-3 C10H12O
1,2-DILINOLEOYL-3-OLEOYL-RAC-GLYCEROL 1,2-DILINOLEOYL-3-OLEOYL-RAC-GLYCEROL 2190-21-8 C57H100O6
FENAMIDONE FENAMIDONE 161326-34-7 C17H17N3OS
2,2',3,3'-TETRACHLOROBIPHENYL 2,2',3,3'-TETRACHLOROBIPHENYL 38444-93-8 C12H6Cl4
CIS-ENTACAPONE CIS-ENTACAPONE 145195-63-7 C14H15N3O5
METHYL OCTACOSANOATE METHYL OCTACOSANOATE 55682-92-3 C29H58O2
CIS-4,7,10,13,16,19-DOCOSAHEXAENOIC ACID METHYL ESTER CIS-4,7,10,13,16,19-DOCOSAHEXAENOIC ACID METHYL ESTER 301-01-9 C23H34O2
Hydroxybupropione Hydroxybupropione 92264-81-8 C13H18ClNO2
3,3',4-TRICHLOROBIPHENYL 3,3',4-TRICHLOROBIPHENYL 37680-69-6 C12H7Cl3
HYDROXY PENTOXIFYLLINE HYDROXY PENTOXIFYLLINE 6493-06-7 C13H20N4O3
2,2',3,5,6-PENTACHLOROBIPHENYL 2,2',3,5,6-PENTACHLOROBIPHENYL 73575-56-1 C12H5Cl5
2,2',3,3',4,4',5,5'-OCTACHLOROBIPHENYL 2,2',3,3',4,4',5,5'-OCTACHLOROBIPHENYL 35694-08-7 C12H2Cl8
2,3,3',4',6-PENTACHLOROBIPHENYL 2,3,3',4',6-PENTACHLOROBIPHENYL 38380-03-9 C12H5Cl5
THEAFLAVINE-3,3'-DIGALLATE THEAFLAVINE-3,3'-DIGALLATE 33377-72-9 C43H32O20
2',3,4,5,6'-PENTACHLOROBIPHENYL 2',3,4,5,6'-PENTACHLOROBIPHENYL 74472-39-2 C12H5Cl5
NBD-COCL NBD-COCL 140164-85-8 C9H7ClN4O4
TRICLOSAN METHYL ETHER TRICLOSAN METHYL ETHER 4640-01-1 C13H9Cl3O2
2,2',4,5-TETRACHLOROBIPHENYL 2,2',4,5-TETRACHLOROBIPHENYL 70362-47-9 C12H6Cl4
(HYDRAZINOCARBONYL)FERROCENE (HYDRAZINOCARBONYL)FERROCENE 12153-28-5 C11H12FeN2O10*
OXADIARGYL  PESTANAL OXADIARGYL PESTANAL 39807-15-3 C15H14Cl2N2O3
DOCOSAHEXAENOIC ACID METHYL ESTER DOCOSAHEXAENOIC ACID METHYL ESTER 2566-90-7 C23H34O2
4-METHYL-5-(SULFOMETHYLAMINO)-2-(2-THIAZ 4-METHYL-5-(SULFOMETHYLAMINO)-2-(2-THIAZ 82138-69-0 C12H12N4O5S2
NIFURPIRINOL NIFURPIRINOL 13411-16-0 C12H10N2O4
ROLITETRACYCLINE ROLITETRACYCLINE 751-97-3 C27H33N3O8
3,5-DICHLOROBIPHENYL 3,5-DICHLOROBIPHENYL 34883-41-5 C12H8Cl2
BETA-ZEARALENOL BETA-ZEARALENOL 71030-11-0 C18H24O5
BENZO(J)FLUORANTHENE BENZO(J)FLUORANTHENE 205-82-3 C20H12
METHYL-D3-MALONIC ACID METHYL-D3-MALONIC ACID 42522-59-8 C4H3D3O4
DPX DPX 14208-10-7 C18H18N2.2Br
BROMOXYNIL-METHYL ETHER BROMOXYNIL-METHYL ETHER 3336-39-8 C8H5Br2NO
2-METHYLISOBORNEOL 2-METHYLISOBORNEOL 2371-42-8 C11H20O
2-HYDROXYESTRADIOL 2-HYDROXYESTRADIOL 362-05-0 C18H24O3
PICENE PICENE 213-46-7 C22H14
2-(hydroxymethyl)-2-methylpentyl isopropyl-carbamate 2-(hydroxymethyl)-2-methylpentyl isopropyl-carbamate 25462-17-3 C11H23NO3
N-Demethyl olanzapine N-Demethyl olanzapine 161696-76-0 C16H18N4S
Ethylhexyl Triazone Ethylhexyl Triazone 88122-99-0 C48H66N6O6
2,2',3,4',5,5',6-HEPTACHLOROBIPHENYL 2,2',3,4',5,5',6-HEPTACHLOROBIPHENYL 52663-68-0 C12H3Cl7
ISOXICAM ISOXICAM 34552-84-6 C14H13N3O5S
2-Methylamino-1-(3',4'-methylenedioxyphenyl)butan-1-one hydrochloride 2-Methylamino-1-(3',4'-methylenedioxyphenyl)butan-1-one hydrochloride 17762-90-2 C12H15NO3.ClH
(-)-CIS-MYRTANOL (-)-CIS-MYRTANOL 51152-12-6 C10H18O
2,3',5,5'-TETRACHLOROBIPHENYL 2,3',5,5'-TETRACHLOROBIPHENYL 41464-42-0 C12H6Cl4
PERTUSSIS TOXIN PERTUSSIS TOXIN 70323-44-3 NULL
1-methyl-3-(9H-thioxanthen-9-ylmethyl)piperidine 1-methyl-3-(9H-thioxanthen-9-ylmethyl)piperidine 7081-40-5 C20H23NS
ISOSTEARIC ACID ISOSTEARIC ACID 2724-58-5 C18H36O2
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