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Analytical Chemistry

Analytical chemistry is the subject for the method and basic principle of studying and identifying of the composition, status, structure of matter as well as determination of related content. It is an important branch of chemistry subject. Analytical chemistry plays an important role in not only its own development but also in various fields related to the chemistry. We can say that all the practice of any human activity involving chemical phenomena is inseparable from analytical chemistry. Now, people have developed various kinds of different analytical methods, which can be classified based on an analysis task, analysis object, the basis of the analysis, requirement of the analysis and sample dosage.

According to the analysis tasks, it can be divided into qualitative analysis, quantitative analysis and structural analysis. Task of qualitative analysis is to identify the elements, radicals, functional groups or compounds that constituting the substances; the task of the quantitative analysis is to determine the content of the related components in the sample; the task of structural analysis is to study the molecular structure or crystal structure of the material.

(1) According to the analysis objects, it can be divided into organic and inorganic analysis; the object for the inorganic analysis is inorganic substance; the object of organic analysis is organic substance. In the inorganic analysis, it is generally required to determine what elements, ions, radicals or compounds that constitutes the sample and measure the percentage of each component; and sometimes it is also necessary for determination of the crystal structure; in the organic analysis, it not only requires the identification of the constituent elements, but also, more importantly, should do the structure analysis and functional group analysis.
(2) According to whether the analysis is based on the physical properties or chemical properties of the substance, it can be divided into instrumental analysis and chemical analysis. Depending on the specific requirements, it can be divided into routine analysis, rapid analysis and arbitration Analysis. Routine analysis refers to the general daily laboratory production analysis, also known as conventional analysis; rapid analysis is a kind of routine analysis and is mainly applied to the control of the production process, demanding the report of the results in the shortest possible time with the error generally being allowed to be greater; arbitration analysis is needed when there is controversy in the analysis results from different institute, demanding related department to conduct accurate analysis using specific method in order to determine the accuracy of the results of the original analysis.
(3) According to the amount of the sample, it can be generally divided into constant (> 0.1g), semi-micro (0.01 ~ 0.1g) and trace (1 ~ 10mg) analysis.
(4) In the inorganic qualitative chemical analysis, people generally apply semi-micro method while people generally apply constant analysis in the quantitative chemical analysis. According to the relative amounts of the analyzed components contained in the sample, it is also roughly divided into constant component analysis (> 1%), minor component analysis (0.01 to 1%) and trace components analysis (<0.01%). For the analysis of some trace amount of components contained in some kinds of complicated mixture and some substances, it is necessary to perform separation and enrichment. This produces a series of separation techniques, such as extraction, distillation, ion exchange, chromatography, sedimentation and flotation separation, these chemical separation techniques are an integral part of the analysis.

Environmental Analytical Chemistry
Environmental Analytical Chemistry is briefly referred to environmental analysis. It is a kind of subject to study the types, components of pollutants in the environment as well as how to perform qualitative and quantitative analysis on the chemical contaminants in the environment. It is a branch of environmental chemistry.

Environmental analytical chemistry emerged, developed and improved during the process of solving environmental problems. In 1950s, the public nuisance disease occurred in Japan had alerted the whole world. In order to find the cause of public nuisance disease, after experiencing as long as 11 years, later, the chemists of environmental analysis had applied light spectrum and identified that the river in Itai-itai disease area contained harmful elements such as lead, cadmium, arsenic and so on. Further by means of tracking element analysis of the soil and food in the disease area, people had found high lead and cadmium content. Later, people had further conducted spectral quantitative analysis on the body and bone of the patients in the disease area and found that the bone ashes contained alarmingly high content of zinc, lead and cadmium. To determine the causative agent, people further incorporated zinc, lead and cadmium into the food for feeding animals and conduct trace elemental analysis for animals and confirmed the serious harm of cadmium on the bone, revealing the cause of the Itai-itai disease. The development of modern science, especially the development of modern chemistry, physics, mathematics, electronics, biology, as well as the emergence of accurate, reliable, sensitive, selective, rapid, simple environmental pollution analysis technology and automation equipment, has been resulting in the maturation of environmental analytical chemistry. Environmental analytical chemistry now has penetrated into all areas of the entire environmental science subject. It is the most effective means of access to environmental information quality.
The objects of the environmental analytical chemistry research are quite complicated, including air, water, soil, sediment, minerals, waste, animals, plants, food, and human tissue. The content of chemical elements or compound to be determined in the environmental analytic chemistry is very low, with the absolute content being within the level of 10-6 to 10-12 grams.


The analysis technology in the environmental analytical chemistry is developing towards the direction of continuous automation, computerization and joint combination of various methods and instruments. Currently applied automatic analysis methods include colorimetric analysis, ion selective electrode, x-ray fluorescence spectroscopy, atomic absorption spectroscopy, polarography, gas chromatography, liquid chromatography and flow injection analysis. Laser, as the light source of analytical chemistry technique, has also been applied. Since the laser analysis has properties of high resolution, high sensitivity, long-range and short-term, the laser technology will play a pivotal role in the development of environmental analytical chemistry.

With the deepened development of environmental science, environmental analytical chemistry is often demanded for trace levels and ultra-trace-level detection and analysis, therefore, high sensitivity. Thus study of analysis methods of high sensitivity, good selectivity, rapid trace and ultra trace will become the major development direction for environmental analysis in the near future.

Qualitative Analysis of Chemistry
Qualitative analytic chemistry is the subject to identify the chemical elements and atoms groups contained in the sample. It is a branch subject of the analysis chemistry. Its purpose is to ascertain the chemical composition of the research object (specimen).
The major research content of the qualitative analytic chemistry includes:

1 the tested samples were analyzed separately. Namely take part of the sample and use exclusive reaction to detect a desire detection component.
2 systematic analysis of the samples. This means successively apply a few selective reactions for gradual separation of the ions followed by separation of each group until separating to only one substance and finally apply confirming reaction to ascertain the existence of this substance. The most famous cation system analysis method is H2S system. In recent years, due to the use of advanced equipment, qualitative analysis has also rapidly developed together with multivariate analysis and has also become an important direction for analytical chemistry.

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Structure Chemical Name CAS MF
BROMODICHLOROACETIC ACID BROMODICHLOROACETIC ACID 71133-14-7 C2HBrCl2O2
WITHAFERIN A WITHAFERIN A 5119-48-2 C28H38O6
AROCLOR 1260, 1X1ML, ISO, 1000UG/ML AROCLOR 1260, 1X1ML, ISO, 1000UG/ML 11096-82-5 C12H4Cl6
Prothioconazole Prothioconazole 178928-70-6 C14H15Cl2N3OS
BACOSIDE A3(P) BACOSIDE A3(P) 157408-08-7 C47H76O18
2,3,4,6-TETRACHLOROBIPHENYL 2,3,4,6-TETRACHLOROBIPHENYL 54230-22-7 C12H6Cl4
6-AMINO-1-PHENALENONE 6-AMINO-1-PHENALENONE 70402-14-1 C13H9NO
ORBENCARB ORBENCARB 34622-58-7 C12H16ClNOS
TRIISONONYL TRIMELLITATE TRIISONONYL TRIMELLITATE 53894-23-8 C36H60O6
4-[2-(DIMETHYLAMINO)ETHYLAMINOSULFONYL]-7-CHLORO-2,1,3-BENZOXADIAZOLE 4-[2-(DIMETHYLAMINO)ETHYLAMINOSULFONYL]-7-CHLORO-2,1,3-BENZOXADIAZOLE 664985-43-7 C10H13ClN4O3S
ALPHA-HYDROXYMETOPROLOL ALPHA-HYDROXYMETOPROLOL 56392-16-6 C15H25NO4
3,3',4,4',5-PENTACHLOROBIPHENYL 3,3',4,4',5-PENTACHLOROBIPHENYL 57465-28-8 C12H5Cl5
2,2',3,4,5-PENTACHLOROBIPHENYL 2,2',3,4,5-PENTACHLOROBIPHENYL 55312-69-1 C12H5Cl5
(+/-)-GEOSMIN (+/-)-GEOSMIN 16423-19-1 C12H22O
2,4'-DICHLOROBIPHENYL 2,4'-DICHLOROBIPHENYL 34883-43-7 C12H8Cl2
2,4,5-T-METHYL ESTER 2,4,5-T-METHYL ESTER 1928-37-6 C9H7Cl3O3
MAGNESIUM PERCHLORATE HYDRATE MAGNESIUM PERCHLORATE HYDRATE 64010-42-0 Cl2H2MgO9
TRIETHYLAMMONIUM PHOSPHATE TRIETHYLAMMONIUM PHOSPHATE 35365-94-7 C6H18NO4P
2-Thiazolidinethione, 3-acetyl- (9CI) 2-Thiazolidinethione, 3-acetyl- (9CI) 76397-53-0 C5H7NOS2
IBUPROFEN SODIUM SALT IBUPROFEN SODIUM SALT 31121-93-4 C13H17NaO2
5-Vinylpyrrolidone 5-Vinylpyrrolidone 7529-16-0 C6H9NO
1,3-BENZODIOXOLE-5,6-DIAMINE DIHYDROCHLORIDE 1,3-BENZODIOXOLE-5,6-DIAMINE DIHYDROCHLORIDE 81864-15-5 C7H10Cl2N2O2
2-(1-METHYL-5-NITRO-1H-IMIDAZOL-2-YL)-PROPAN-2-OL 2-(1-METHYL-5-NITRO-1H-IMIDAZOL-2-YL)-PROPAN-2-OL 35175-14-5 C7H11N3O3
EPA EPA 73167-03-0 C20H29O2.Na
10-METHYLUNDECANOIC ACID 10-METHYLUNDECANOIC ACID 2724-56-3 C12H24O2
2,3',4,5',6-PENTACHLOROBIPHENYL 2,3',4,5',6-PENTACHLOROBIPHENYL 56558-18-0 C12H5Cl5
OXY-CHLORDANE OXY-CHLORDANE 27304-13-8 C10H4Cl8O
AMBERLITE(R) XAD-1180 AMBERLITE(R) XAD-1180 9003-69-4 C10H10
3-HYDROXYHEXADECANOIC ACID 3-HYDROXYHEXADECANOIC ACID 928-17-6 C16H32O3
4-[N-(2,4-DIAMINO-6-PTERIDINYLMETHYL)-N-METHYLAMINO] BENZOIC ACID 4-[N-(2,4-DIAMINO-6-PTERIDINYLMETHYL)-N-METHYLAMINO] BENZOIC ACID 19741-14-1 C15H15N7O2
TEPRALOXYDIM TEPRALOXYDIM 149979-41-9 C17H24ClNO4
3-AMINO-2-OXAZOLIDINONE D4 3-AMINO-2-OXAZOLIDINONE D4 1188331-23-8 C3H2D4N2O2
CYNARIN CYNARIN 19870-46-3 C25H24O12
DIETHYLTIN DICHLORIDE DIETHYLTIN DICHLORIDE 866-55-7 C4H10Cl2Sn
Di-tert-butyl Chloromethyl Phosphate Di-tert-butyl Chloromethyl Phosphate 229625-50-7 C9H20ClO4P
2-HYDROXYDODECANOIC ACID 2-HYDROXYDODECANOIC ACID 2984-55-6 C12H24O3
2,3,4,5,6-Pentabromoethylbenzene 2,3,4,5,6-Pentabromoethylbenzene 85-22-3 C8H5Br5
FLUORANTHENE-D10 FLUORANTHENE-D10 93951-69-0 C16D10
2,2',3,3',4,5',6,6'-OCTACHLOROBIPHENYL 2,2',3,3',4,5',6,6'-OCTACHLOROBIPHENYL 40186-71-8 C12H2Cl8
M-3-G HYDRATE M-3-G HYDRATE 20290-09-9 C23H27NO9
PROPYLENE GLYCOL MONOLAURATE PROPYLENE GLYCOL MONOLAURATE 27194-74-7 C15H30O3
Dibutyl butanephosphonate Dibutyl butanephosphonate 78-46-6 C12H27O3P
CHLORBENSIDE CHLORBENSIDE 103-17-3 C13H10Cl2S
2,3,6-TRICHLOROANISOLE 2,3,6-TRICHLOROANISOLE 50375-10-5 C7H5Cl3O
NIVALENOL NIVALENOL 23282-20-4 C15H20O7
(S)-(+)-N-(3,5-DINITROBENZOYL)-ALPHA-PHENYLETHYLAMINE (S)-(+)-N-(3,5-DINITROBENZOYL)-ALPHA-PHENYLETHYLAMINE 69632-31-1 C15H13N3O5
INDENO(1,2,3-C,D)FLUORANTHENE INDENO(1,2,3-C,D)FLUORANTHENE 193-43-1 C22H12
2,2',3,3',4,4'-HEXACHLOROBIPHENYL 2,2',3,3',4,4'-HEXACHLOROBIPHENYL 38380-07-3 C12H4Cl6
2,2',3,3',4,4',5,6,6'-NONACHLOROBIPHENYL 2,2',3,3',4,4',5,6,6'-NONACHLOROBIPHENYL 52663-79-3 C12HCl9
1,2,3,9-TETRAHYDRO-9-METHTYL-3-METHYLENE-4H-CARBAZOL-4-ONE 1,2,3,9-TETRAHYDRO-9-METHTYL-3-METHYLENE-4H-CARBAZOL-4-ONE 99614-64-9 C14H13NO
COAGULATION FACTOR VII, HUMAN COAGULATION FACTOR VII, HUMAN 9001-25-6
4-METHYLCHRYSENE 4-METHYLCHRYSENE 3351-30-2 C19H14
Rutin trihydrate Rutin trihydrate 250249-75-3 C27H30O163H2O
4-(4-chlorophenyl)-1-[4-(4-fluorophenyl)-4-oxobutyl]-4-piperidyl decanoate 4-(4-chlorophenyl)-1-[4-(4-fluorophenyl)-4-oxobutyl]-4-piperidyl decanoate 74050-97-8 C31H41ClFNO3
3,4,4'-TRICHLOROBIPHENYL 3,4,4'-TRICHLOROBIPHENYL 38444-90-5 C12H7Cl3
3-ACETYLDEOXYNIVALENOL 3-ACETYLDEOXYNIVALENOL 50722-38-8 C17H22O7
2,2',4,4',6,6'-HEXACHLOROBIPHENYL 2,2',4,4',6,6'-HEXACHLOROBIPHENYL 33979-03-2 C12H4Cl6
4-BIPHENYLALDEHYDE OXIME 4-BIPHENYLALDEHYDE OXIME 40143-27-9 C13H11NO
ZOPICLONE N-OXIDE ZOPICLONE N-OXIDE 43200-96-0 C17H17ClN6O4
ALPHA-[BUTYLAMINO]METHYL-P-HYDROXYBENZYL ALCOHOL ALPHA-[BUTYLAMINO]METHYL-P-HYDROXYBENZYL ALCOHOL 5716-20-1 C12H21NO6S
OCTANOIC-D15 ACID OCTANOIC-D15 ACID 69974-55-6 C8HD15O2
ARACHIDONIC ACID SODIUM SALT ARACHIDONIC ACID SODIUM SALT 6610-25-9 C20H31NaO2
BROMOPYRAZONE BROMOPYRAZONE 3042-84-0 C10H8BrN3O
PERYLENE-D12 PERYLENE-D12 1520-96-3 C20H12
DABSYL HYDRAZINE DABSYL HYDRAZINE 72565-41-4 C14H17N5O2S
ETHYLENE DI(THIOTOSYLATE) ETHYLENE DI(THIOTOSYLATE) 2225-23-2 C16H18O4S4
BENFLUOREX HYDROCHLORIDE BENFLUOREX HYDROCHLORIDE 23602-78-0 C19H20F3NO2
ETHYL B-D-GLUCURONIDE ETHYL B-D-GLUCURONIDE 17685-04-0 C8H14O7
SALVINORIN A SALVINORIN A 83729-01-5 C23H28O8
(R)-(-)-NBD-APY (R)-(-)-NBD-APY 143112-51-0 C10H11N5O3
(-)-ALPHA-BISABOLOL (-)-ALPHA-BISABOLOL 22567-36-8 C15H26O2
THIOMETON THIOMETON 640-15-3 C6H15O2PS3
7-(DIETHYLAMINO)COUMARIN-3-CARBOHYDRAZIDE 7-(DIETHYLAMINO)COUMARIN-3-CARBOHYDRAZIDE 100343-98-4 C14H17N3O3
2,3,5,6-TETRACHLOROBIPHENYL 2,3,5,6-TETRACHLOROBIPHENYL 33284-54-7 C12H6Cl4
METHYL ARACHIDONATE METHYL ARACHIDONATE 2566-89-4 C21H34O2
4-(N-NITROSOMETHYLAMINO)-1-(3-PYRIDYL)-1-BUTANONE 4-(N-NITROSOMETHYLAMINO)-1-(3-PYRIDYL)-1-BUTANONE 64091-91-4 C10H13N3O2
BISPHENOL A-D16 BISPHENOL A-D16 96210-87-6 C15H16O2
N-CHLOROMETHYL-4-NITROPHTHALIMIDE N-CHLOROMETHYL-4-NITROPHTHALIMIDE 54455-34-4 C9H5ClN2O4
NORFLUOXETINE HYDROCHLORIDE NORFLUOXETINE HYDROCHLORIDE 57226-68-3 C16H17ClF3NO
2,2',4,5'-TETRACHLOROBIPHENYL 2,2',4,5'-TETRACHLOROBIPHENYL 41464-40-8 C12H6Cl4
2,3'-DICHLOROBIPHENYL 2,3'-DICHLOROBIPHENYL 25569-80-6 C12H8Cl2
CUMYLURON CUMYLURON 99485-76-4 C17H19ClN2O
DALAPON-METHYL ESTER DALAPON-METHYL ESTER 17640-02-7 C4H6Cl2O2
Atorvastatin hemicalcium trihydrate Atorvastatin hemicalcium trihydrate 344423-98-9 C66H74CaF2N4O13
PROTHOATE PROTHOATE 2275-18-5 C9H20NO3PS2
2-Ethylhexyl 2-(2,4-dichlorophenoxy)propionate 2-Ethylhexyl 2-(2,4-dichlorophenoxy)propionate 79270-78-3 C17H24Cl2O3
HEXADECANOIC ACID-1-13C HEXADECANOIC ACID-1-13C 57677-53-9 C16H32O2
DBD-ED DBD-ED 189373-41-9 C10H15N5O3S
ENDOSULFAN ETHER ENDOSULFAN ETHER 3369-52-6 C9H6Cl6O
DIMETHYL HEXADECANEDIOATE DIMETHYL HEXADECANEDIOATE 19102-90-0 C18H34O4
1-(4-NITROBENZYL)-3-P-TOLYLTRIAZENE 1-(4-NITROBENZYL)-3-P-TOLYLTRIAZENE 60259-80-5 C14H14N4O2
2,3,4-TRICHLOROBIPHENYL 2,3,4-TRICHLOROBIPHENYL 55702-46-0 C12H7Cl3
BENZOYLECGONINE BENZOYLECGONINE 519-09-5 C16H19NO4
2,2',3,3',4,4',5,5',6-NONACHLOROBIPHENYL 2,2',3,3',4,4',5,5',6-NONACHLOROBIPHENYL 40186-72-9 C12HCl9
TWEEN 85 TWEEN 85 9055-70-3 C60H108O8.(C2H4O)n
2-(Methylamino)-1-(4-methylphenyl)-1-propanone hydrochloride 2-(Methylamino)-1-(4-methylphenyl)-1-propanone hydrochloride 1189726-22-4 C11H15NO.HCl
TETRASUL TETRASUL 2227-13-6 C12H6Cl4S
DIMETHYL BRASSYLATE DIMETHYL BRASSYLATE 1472-87-3 C15H28O4
RETRORSINE RETRORSINE 480-54-6 C18H25NO6
(1'R,3'S,3S,5R,6R)-5-AMINO-2-AMINOMETHYL-6-(4,6-DIAMINO-2,3-DIHYDROXY-CYCLOHEXYLOXY)-TETRAHYDRO-PYRAN-3,4-DIOL (1'R,3'S,3S,5R,6R)-5-AMINO-2-AMINOMETHYL-6-(4,6-DIAMINO-2,3-DIHYDROXY-CYCLOHEXYLOXY)-TETRAHYDRO-PYRAN-3,4-DIOL 3947-65-7 C12H26N4O6
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