N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine synthesis
- Product Name:N-(4-BroMophenyl)-N,N-bis(1,1'-biphenyl-4-yl)aMine
- CAS Number:499128-71-1
- Molecular formula:C30H22BrN
- Molecular Weight:476.41
589-87-7
540 suppliers
$10.00/1g
102113-98-4
308 suppliers
$6.00/1g
499128-71-1
167 suppliers
$7.00/100mg
Yield:499128-71-1 94%
Reaction Conditions:
with 1,10-Phenanthroline;potassium hydroxide;copper dichloride in toluene for 12 h;
Steps:
10.2; 11.2
(2) 30.53g (0.095mol) of bis([1,1'-biphenyl]-4-yl)amine (MW: 321.42),P-bromoiodobenzene (MW: 282.91) 26.88g (0.095mol),Cuprous chloride (MW: 99.00) 6.02g (0.0608mol),1,10-phenanthroline (MW: 180.2) 6.16g (0.0342mol),Potassium hydroxide (MW: 56) 31.92g (0.57mol) and toluene 530mL,Put it in a 1L reaction flask,Backflow diversion,Reaction for 12h; after the reaction is over,Cool down,filter,Wash with water to neutral, remove solvent,Dry to obtain N-([1,1'-biphenyl]-4-yl)-N-(4-bromophenyl)-[1,1'-biphenyl]-4-amine (MW: 476.42) 42.54g (0.0893mol), yield 94%;
References:
Yantai Xianhua Optoelectric Materials Institute Co., Ltd.;Sun Wei;Feng Peichuan;Chen Yue;Hu Lingfeng;Chen Yili;Wei Peng;Yang Yang CN111484468, 2020, A Location in patent:Paragraph 0105-0108; 0110; 0113-0116; 0118
![N-[1,1-biphenyl]-4-yl-N-phenyl-[1,1-Biphenyl]-4-amine](/CAS/20180703/GIF/122215-84-3.gif)
122215-84-3
45 suppliers
$28.00/250mg
499128-71-1
167 suppliers
$7.00/100mg
106-37-6
487 suppliers
$9.00/5g
102113-98-4
308 suppliers
$6.00/1g
499128-71-1
167 suppliers
$7.00/100mg
1591-31-7
337 suppliers
$8.00/5g
106-40-1
489 suppliers
$12.00/5g
499128-71-1
167 suppliers
$7.00/100mg
92-66-0
578 suppliers
$10.00/1g
106-40-1
489 suppliers
$12.00/5g
499128-71-1
167 suppliers
$7.00/100mg