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1-Bromo-4-iodobenzene

1-Bromo-4-iodobenzene structure

CAS No.: 589-87-7

Chemical Name:: 1-Bromo-4-iodobenzene

Synonyms: P-BROMOIODOBENZENE;4-BROMOIODOBENZENE;4-BroMoiodoben;p-Bromiodobenzene;4-IODOBROMOBENZENE;p-Iodobromobenzene;4- Bromiodobenzene;1-Brom-4-iodbenzol;1-BROMO-IODOBENZENE;4-Bromophenyl iodide

CBNumber:: CB4266086

Molecular Formula:: C6H4BrI

Molecular Weight:: 282.9

MDL Number:: MFCD00001051

MOL File:: 589-87-7.mol

Last updated:2025-03-10 17:18:44

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1-Bromo-4-iodobenzene Properties

Melting point	89-91 °C(lit.)
Boiling point	120-122 °C14 mm Hg(lit.)
Density	2.2236 (rough estimate)
refractive index	1.6618 (estimate)
Flash point	120-122°C/14mm
storage temp.	Store below +30°C.
solubility	0.008g/l
form	Crystalline Powder, Crystals or Needles
color	White to brown
Water Solubility	Insoluble in water.
Sensitive	Light Sensitive
BRN	1904545
InChIKey	UCCUXODGPMAHRL-UHFFFAOYSA-N
CAS DataBase Reference	589-87-7(CAS DataBase Reference)
FDA UNII	R9LDG2XS7C
NIST Chemistry Reference	Benzene, 1-bromo-4-iodo-(589-87-7)
EPA Substance Registry System	Benzene, 1-bromo-4-iodo- (589-87-7)
UNSPSC Code	12352101
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319

Precautionary statements

P302+P352-P305+P351+P338

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-36-37/39

WGK Germany

Hazard Note

Harmful/Light Sensitive

TSCA

HazardClass

IRRITANT, LIGHT SENSITIVE, IRRITANT-HARMFUL

HS Code

29036990

NFPA 704

	1
2		0

1-Bromo-4-iodobenzene price More Price(35)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	238090	1-Bromo-4-iodobenzene 98%	589-87-7	5g	$30.1	2024-03-01	Buy
Sigma-Aldrich	238090	1-Bromo-4-iodobenzene 98%	589-87-7	25g	$143	2024-03-01	Buy
TCI Chemical	B0604	1-Bromo-4-iodobenzene	589-87-7	25G	$71	2024-03-01	Buy
TCI Chemical	B0604	1-Bromo-4-iodobenzene	589-87-7	250G	$425	2024-03-01	Buy
Alfa Aesar	A13859	1-Bromo-4-iodobenzene, 98%	589-87-7	10g	$53.3	2024-03-01	Buy

Product number	Packaging	Price	Buy
238090	5g	$30.1	Buy
238090	25g	$143	Buy
B0604	25G	$71	Buy
B0604	250G	$425	Buy
A13859	10g	$53.3	Buy

1-Bromo-4-iodobenzene Chemical Properties,Uses,Production

Synthesis methods

Industrial parabromoaniline is as raw material, by diazotization, iodo-synthesis of bromo iodobenzene. Preferred synthesis conditions: firstly 0.02mol parabromoaniline is dissolved in a mass fraction of 20% sulfuric acid medium, then reacts with 0.021molNaNO2 to generate bromophenyl diazonium sulfate at-10℃, and then chloroform and 0.021molKI is added into solution to process iodination reaction, after simple treatment bromo-iodobenzene crude product (which the bromo-iodobenzene HPLC purity 98.4%) is obtained, total yield after purification is 80%, increases by 15% than before improved. The product processes structural characterization by IR and 1HNMR. The improved method can greatly improve the purity of the crude product, this avoids the trouble of going through the column, this method is safe and easy to operate, easy to control the process, cost is lower, it is more suitable for the preparation of 1-Bromo-4-iodobenzene.
Unit: Heilongjiang University of Chemistry and Materials Science
Author: Guo Jing Bai Xuefeng Lvhong Fei

Uses

1. 1-Bromo-4-iodobenzene is used for organic synthesis.
2. Used as substrate for copper-free Sonogashira coupling reaction in aqueous acetone.
3. For the synthesis of β,β-dibromostyrene.

Chemical Properties

white to brown cryst. powder, crystals or needles

Uses

suzuki reaction

Uses

1-Bromo-4-iodobenzene has been employed:

as reagent for in situ desilylation and coupling of silylated alkynes
as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids)
as substrate in copper-free Sonogashira coupling in aqueous acetone
in synthesis of β,β,dibromostyrenes

General Description

Vapour pressure as a function of temperature for 1-bromo-4-iodobenzene has been studied using a diaphragm manometer and torsion mass-loss effusion.

1-Bromo-4-iodobenzene synthesis

Synthesis of 1-Bromo-4-iodobenzene from 4-BROMOBENZENEDIAZONIUM TETRAFLUOROBORATE

1-Bromo-4-iodobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

4-Bromophenoxybenzene (E)-METHYL 3-(4-BROMOPHENYL)ACRYLATE 4-Bromobenzaldehyde 1-(4-Bromophenyl)-naphthlene 4-(NAPHTHALEN-2-YL)PHENYLBORONIC ACID

4-BROMOBENZENESULFONIC ACID MONOHYDRATE 1-Bromo-4-propylbenzene 2-(4-bromophenyl)-1,3,4-oxadiazole (9-(4-BROMOPHENYL))-9H-CARBAZOLE 1 4-BIS(DIPHENYLAMINO)BENZENE

4-BROMODIPHENYLMETHANE METHYL 4'-BROMO[1,1'-BIPHENYL]-4-CARBOXYLATE 1,4-BIS(PHENYLETHYNYL)BENZENE 4-(P-IODOPHENYL)BUTYRIC ACID 9-(1,1-bipheny)-4-yl-3-(4-broMophenyl)carbazole

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1-Bromo-4-iodobenzene Suppliers

Global( 656)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Nanjing Shunxiang Pharmaceutical Technology Co.,Ltd.	+86-86-02586819868 +8613913839793	sales@jinchemical.com	China	23	58
Shandong Dinghao Biological Technology Co. LTD	+86-86-18300239 +8618300239268	sales@sddhpharm.com	China	101	58
Hebei Chuanghai Biotechnology Co., Ltd	+8617732866630	abby@chuanghaibio.com	China	8773	58
Hebei Chuanghai Biotechnology Co,.LTD	+86-13131129325	sales1@chuanghaibio.com	China	5251	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20202	58
Hebei Zhuanglai Chemical Trading Co Ltd	+86-16264648883	niki@zlchemi.com	China	7245	58
Springchem New Material Technology Co.,Limited	+86-021-62885108 +8613917661608	info@spring-chem.com	China	2068	57
Capot Chemical Co.,Ltd.	+8613336195806	sales@capot.com	China	29731	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	12828	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21622	55

Supplier	Advantage
Nanjing Shunxiang Pharmaceutical Technology Co.,Ltd.	58
Shandong Dinghao Biological Technology Co. LTD	58
Hebei Chuanghai Biotechnology Co., Ltd	58
Hebei Chuanghai Biotechnology Co,.LTD	58
Henan Fengda Chemical Co., Ltd	58
Hebei Zhuanglai Chemical Trading Co Ltd	58
Springchem New Material Technology Co.,Limited	57
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55

View Lastest Price from 1-Bromo-4-iodobenzene manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-07-30	1-Bromo-4-iodobenzene 589-87-7	US $25.00 / KG	1KG	98%+	300MT/year	Speranza Chemical Co., Ltd.
2025-07-07	4-Bromoiodobenzene 589-87-7	US $100.00 / kg	1kg	99%	50000KG/month	Hebei Mujin Biotechnology Co.,Ltd
2025-07-07	1-Bromo-4-iodobenzene 589-87-7	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mujin Biotechnology Co.,Ltd

1-Bromo-4-iodobenzene
589-87-7
US $25.00 / KG
98%+
Speranza Chemical Co., Ltd.

4-Bromoiodobenzene
589-87-7
US $100.00 / kg
99%
Hebei Mujin Biotechnology Co.,Ltd

1-Bromo-4-iodobenzene
589-87-7
US $0.00 / KG
99%
Hebei Mujin Biotechnology Co.,Ltd

1-Bromo-4-iodobenzene Spectrum

1-Bromo-4-iodobenzene(589-87-7)MS 1-Bromo-4-iodobenzene(589-87-7)¹HNMR 1-Bromo-4-iodobenzene(589-87-7)¹³CNMR 1-Bromo-4-iodobenzene(589-87-7)IR1 1-Bromo-4-iodobenzene(589-87-7)IR2 1-Bromo-4-iodobenzene(589-87-7)IR3 1-Bromo-4-iodobenzene(589-87-7)Raman

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benzene,1-broMo-4-iodo- 1-BroMo-4-iodobenzene, 98% 25GR 1-Brom-4-iodobenzene 4-Bromoiodobenzene 99+% 4-BroMoiodobenzene, 97+% 4-BroMoiodoben The broMine iodobenzene 4-Bromoiodobenzene p-Bromoiodobenzene 4-Bromo-1-iodobenzene for synthesis 4-Bromophenyl iodide 4-Iodo-1-bromobenzene 4-Iodophenyl bromide 4-IODOBROMOBENZENE 4-BROMO-1-IODOBENZENE 1-BROMO-4-IODOBENZENE 1-bromo-4-iodo-benzen p-Bromophenyl iodide p-Iodobromobenzene 1-bromo-4-oiodobenzene 1-Bromo-4-iodobenzene,98% p-Bromoiodobenzene 1-Bromo-4-Iodo Benzene p-Bromiodobenzene 1-BROMO-IODOBENZENE 1-Bromo-4-Iodobenzene>99% 1-Bromo-4-iodobenzene, 97+% 1,4-bromoiodobenzene 4-Bromoiodobenzene 98% Vortioxetine Impurity 53 1-Bromo-4-iodobenzene > 4- Bromiodobenzene 1-Bromo-4-iodobenzene ISO 9001：2015 REACH 4-BROMOIODOBENZENE P-BROMOIODOBENZENE 4-Bromoiodobenzene CAS 4-Bromiodobenzene (4-Bromiodobenzene) 1-Brom-4-iodbenzol 589-87-7 C6H4BrI ARYL HALIDE Organic Building Blocks Halogenated Hydrocarbons Building Blocks Aryl C6 Building Blocks Chemical Synthesis Halogenated Hydrocarbons Organic Building Blocks alkyl Iodine|alkyl bromide Halogenated benzene series Miscellaneous Benzene derivates Bromine Compounds Iodine Compounds Light yellow crystalline powder Aryl Halogenated Hydrocarbons bc0001

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1-Bromo-4-iodobenzene

1-Bromo-4-iodobenzene Properties

SAFETY

Risk and Safety Statements

1-Bromo-4-iodobenzene price More Price(35)

1-Bromo-4-iodobenzene Chemical Properties,Uses,Production

Synthesis methods

Uses

Chemical Properties

Uses

Uses

General Description

1-Bromo-4-iodobenzene synthesis

1-Bromo-4-iodobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

1-Bromo-4-iodobenzene Suppliers

View Lastest Price from 1-Bromo-4-iodobenzene manufacturers

1-Bromo-4-iodobenzene Spectrum

589-87-7(1-Bromo-4-iodobenzene)Related Search: