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Analytical Chemistry

Analytical chemistry is the subject for the method and basic principle of studying and identifying of the composition, status, structure of matter as well as determination of related content. It is an important branch of chemistry subject. Analytical chemistry plays an important role in not only its own development but also in various fields related to the chemistry. We can say that all the practice of any human activity involving chemical phenomena is inseparable from analytical chemistry. Now, people have developed various kinds of different analytical methods, which can be classified based on an analysis task, analysis object, the basis of the analysis, requirement of the analysis and sample dosage.

According to the analysis tasks, it can be divided into qualitative analysis, quantitative analysis and structural analysis. Task of qualitative analysis is to identify the elements, radicals, functional groups or compounds that constituting the substances; the task of the quantitative analysis is to determine the content of the related components in the sample; the task of structural analysis is to study the molecular structure or crystal structure of the material.

(1) According to the analysis objects, it can be divided into organic and inorganic analysis; the object for the inorganic analysis is inorganic substance; the object of organic analysis is organic substance. In the inorganic analysis, it is generally required to determine what elements, ions, radicals or compounds that constitutes the sample and measure the percentage of each component; and sometimes it is also necessary for determination of the crystal structure; in the organic analysis, it not only requires the identification of the constituent elements, but also, more importantly, should do the structure analysis and functional group analysis.
(2) According to whether the analysis is based on the physical properties or chemical properties of the substance, it can be divided into instrumental analysis and chemical analysis. Depending on the specific requirements, it can be divided into routine analysis, rapid analysis and arbitration Analysis. Routine analysis refers to the general daily laboratory production analysis, also known as conventional analysis; rapid analysis is a kind of routine analysis and is mainly applied to the control of the production process, demanding the report of the results in the shortest possible time with the error generally being allowed to be greater; arbitration analysis is needed when there is controversy in the analysis results from different institute, demanding related department to conduct accurate analysis using specific method in order to determine the accuracy of the results of the original analysis.
(3) According to the amount of the sample, it can be generally divided into constant (> 0.1g), semi-micro (0.01 ~ 0.1g) and trace (1 ~ 10mg) analysis.
(4) In the inorganic qualitative chemical analysis, people generally apply semi-micro method while people generally apply constant analysis in the quantitative chemical analysis. According to the relative amounts of the analyzed components contained in the sample, it is also roughly divided into constant component analysis (> 1%), minor component analysis (0.01 to 1%) and trace components analysis (<0.01%). For the analysis of some trace amount of components contained in some kinds of complicated mixture and some substances, it is necessary to perform separation and enrichment. This produces a series of separation techniques, such as extraction, distillation, ion exchange, chromatography, sedimentation and flotation separation, these chemical separation techniques are an integral part of the analysis.

Environmental Analytical Chemistry
Environmental Analytical Chemistry is briefly referred to environmental analysis. It is a kind of subject to study the types, components of pollutants in the environment as well as how to perform qualitative and quantitative analysis on the chemical contaminants in the environment. It is a branch of environmental chemistry.

Environmental analytical chemistry emerged, developed and improved during the process of solving environmental problems. In 1950s, the public nuisance disease occurred in Japan had alerted the whole world. In order to find the cause of public nuisance disease, after experiencing as long as 11 years, later, the chemists of environmental analysis had applied light spectrum and identified that the river in Itai-itai disease area contained harmful elements such as lead, cadmium, arsenic and so on. Further by means of tracking element analysis of the soil and food in the disease area, people had found high lead and cadmium content. Later, people had further conducted spectral quantitative analysis on the body and bone of the patients in the disease area and found that the bone ashes contained alarmingly high content of zinc, lead and cadmium. To determine the causative agent, people further incorporated zinc, lead and cadmium into the food for feeding animals and conduct trace elemental analysis for animals and confirmed the serious harm of cadmium on the bone, revealing the cause of the Itai-itai disease. The development of modern science, especially the development of modern chemistry, physics, mathematics, electronics, biology, as well as the emergence of accurate, reliable, sensitive, selective, rapid, simple environmental pollution analysis technology and automation equipment, has been resulting in the maturation of environmental analytical chemistry. Environmental analytical chemistry now has penetrated into all areas of the entire environmental science subject. It is the most effective means of access to environmental information quality.
The objects of the environmental analytical chemistry research are quite complicated, including air, water, soil, sediment, minerals, waste, animals, plants, food, and human tissue. The content of chemical elements or compound to be determined in the environmental analytic chemistry is very low, with the absolute content being within the level of 10-6 to 10-12 grams.


The analysis technology in the environmental analytical chemistry is developing towards the direction of continuous automation, computerization and joint combination of various methods and instruments. Currently applied automatic analysis methods include colorimetric analysis, ion selective electrode, x-ray fluorescence spectroscopy, atomic absorption spectroscopy, polarography, gas chromatography, liquid chromatography and flow injection analysis. Laser, as the light source of analytical chemistry technique, has also been applied. Since the laser analysis has properties of high resolution, high sensitivity, long-range and short-term, the laser technology will play a pivotal role in the development of environmental analytical chemistry.

With the deepened development of environmental science, environmental analytical chemistry is often demanded for trace levels and ultra-trace-level detection and analysis, therefore, high sensitivity. Thus study of analysis methods of high sensitivity, good selectivity, rapid trace and ultra trace will become the major development direction for environmental analysis in the near future.

Qualitative Analysis of Chemistry
Qualitative analytic chemistry is the subject to identify the chemical elements and atoms groups contained in the sample. It is a branch subject of the analysis chemistry. Its purpose is to ascertain the chemical composition of the research object (specimen).
The major research content of the qualitative analytic chemistry includes:

1 the tested samples were analyzed separately. Namely take part of the sample and use exclusive reaction to detect a desire detection component.
2 systematic analysis of the samples. This means successively apply a few selective reactions for gradual separation of the ions followed by separation of each group until separating to only one substance and finally apply confirming reaction to ascertain the existence of this substance. The most famous cation system analysis method is H2S system. In recent years, due to the use of advanced equipment, qualitative analysis has also rapidly developed together with multivariate analysis and has also become an important direction for analytical chemistry.

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Structure Chemical Name CAS MF
Silylating mixture Fluka III
		
	Silylating mixture Fluka III
8(Z)-Octadecenoic acid Methyl Ester 8(Z)-Octadecenoic acid Methyl Ester C19H36O2
3-[3-(diMethylaMino)-1-propyl](4-fluorophenyl)-6-cyano-1(3H)-isobenzofuranone oxalate 3-[3-(diMethylaMino)-1-propyl](4-fluorophenyl)-6-cyano-1(3H)-isobenzofuranone oxalate C22H21FN2O6
S-Metolachlor CGA 368208 S-Metolachlor CGA 368208 1173021-76-5 C11H14NNaO4S
6(Z),9(Z),12(Z),15(Z),18(Z)-Heneicosapentaenoic acid methyl 6(Z),9(Z),12(Z),15(Z),18(Z)-Heneicosapentaenoic acid methyl
Anastrozole iMpurity E Anastrozole iMpurity E
MefenaMic acid-13C6 MefenaMic acid-13C6 1325559-19-0 C15H15NO2
SulfadiMethoxine-13C6 SulfadiMethoxine-13C6 1334378-48-1 C12H14N4O4S
TolfenaMic acid-13C6 TolfenaMic acid-13C6 1420043-61-3 C14H12ClNO2
CitalopraM Related CoMpound G CitalopraM Related CoMpound G
Fluticasone Propionate Resolution Mixture Fluticasone Propionate Resolution Mixture C28H35F3O6S
Levothyroxine for Peak Identification Levothyroxine for Peak Identification
Orlistat Related CoMpound E Orlistat Related CoMpound E
SuMatriptan Succinate Related CoMpound C SuMatriptan Succinate Related CoMpound C
Pefloxacin-D5 Pefloxacin-D5 1228182-51-1 C17H20FN3O3
Toltrazuril sulfone-D3
Ponazuril-D3 Toltrazuril sulfone-D3 Ponazuril-D3 1346602-48-9 C18H14F3N3O6S
Sodium azide-1-15N (terminal N) Sodium azide-1-15N (terminal N)
Sulfachloropyridazine-phenyl-13C6 Sulfachloropyridazine-phenyl-13C6
Heater  block Heater block
Copper(II)  electrolyte  buffer  pH  3.0  for  cation-HPCE Copper(II) electrolyte buffer pH 3.0 for cation-HPCE
EPA  TO-11A  Six  Component  Carbonyl-DNPH  Mix EPA TO-11A Six Component Carbonyl-DNPH Mix
EPA  TCLP  Acids  Mix EPA TCLP Acids Mix
Model  226  Pressure  Regulator Model 226 Pressure Regulator
Single  cell  protein  (trace  elements) Single cell protein (trace elements)
Cod  liver  oil  (PCBs) Cod liver oil (PCBs)
JMHW  VOC  Mix JMHW VOC Mix
Ethanol  in  water  (SNIF) Ethanol in water (SNIF)
EPA  1311  Base-Neutrals  Mix EPA 1311 Base-Neutrals Mix
Cobalt  Standard  for  ICP Cobalt Standard for ICP Co
Nickel  matrix  modifier  solution Nickel matrix modifier solution Ni
Nitrite  standard  for  IC Nitrite standard for IC NO2-
TLC  plate  holder TLC plate holder
JP-5  Military  Fuel  solution JP-5 Military Fuel solution
4-Amino-2,6-dinitrotoluene  solution 4-Amino-2,6-dinitrotoluene solution C7H7N3O4
Sewage  sludge  (content  in  PCDDs,  PCDFs) Sewage sludge (content in PCDDs, PCDFs)
Low  volatile  steam  coal  (S) Low volatile steam coal (S)
BTEX  Mix,  HC BTEX Mix, HC
Pesticide  Resolution  Check  Mix-A Pesticide Resolution Check Mix-A
No.  3  Fuel  Oil No. 3 Fuel Oil
Ochratoxin  A13C20  solution Ochratoxin A13C20 solution 911392-42-2 C20H18ClNO6
Cell  holder Cell holder
Wine  (EtOH,  low  level) Wine (EtOH, low level)
EPA  8240B  Calibration  Mix  7 EPA 8240B Calibration Mix 7
GRO  Mix GRO Mix
Zinc  67Zn  solution  (certified  for  isotope  abundance  ratio) Zinc 67Zn solution (certified for isotope abundance ratio) Zn
Nitrate Ionophore VI
		
	Nitrate Ionophore VI 1196157-85-3 C28H60N4O4
Fluoxetine-d5 solution
		
	Fluoxetine-d5 solution 1173147-79-9 C17H17DF3NO
Erbium(III) Ionophore I
		
	Erbium(III) Ionophore I 104662-64-8 C21H18N2O2
Tin(II) ionophore III
		
	Tin(II) ionophore III 1173985-63-1 C48H48N4O3
trans-9-Hexadecenoic acid-1,2,3,7,8-13C5
		
	trans-9-Hexadecenoic acid-1,2,3,7,8-13C5 1255644-44-0 C16H30O2
5a,6-Dihydro-5a,6,6-trimethyl-2,8-dinitro-12H-indolo[2,1-b][1,3]benzoxazine
		
	5a,6-Dihydro-5a,6,6-trimethyl-2,8-dinitro-12H-indolo[2,1-b][1,3]benzoxazine 1023640-20-1 C18H17N3O5
Viscosity and Density Standard
		
	Viscosity and Density Standard
Sulphated β-cyclodextrin, 100mg, neat
		
	Sulphated β-cyclodextrin, 100mg, neat
EPA TO-14A Reactive Subset Mix
		
	EPA TO-14A Reactive Subset Mix
AQUANAL(R)-PLUS CARBONATE HARDNESS CHECKING SOLUTION AQUANAL(R)-PLUS CARBONATE HARDNESS CHECKING SOLUTION
AQUANAL-PLUS NITRITE AQUANAL-PLUS NITRITE
Methyl20-Hydroxyeicosanate Methyl20-Hydroxyeicosanate
HYDRANALCOULOMATAK HYDRANALCOULOMATAK
SILICA GEL 100 CN SILICA GEL 100 CN
picotamide monohydrate picotamide monohydrate 80530-63-8
EUROSOIL 4 EUROSOIL 4
Flow  adapter  for  Luer  lock  LC  columns Flow adapter for Luer lock LC columns
Soya  356043  GMO  standard  ERM-BF425 Soya 356043 GMO standard ERM-BF425
Aroclor  Spike  Mix Aroclor Spike Mix
Manganese  AA/ICP  calibration/check  standard  for  environmental  analysis Manganese AA/ICP calibration/check standard for environmental analysis
EPA  8080  System  Evaluation  Mix EPA 8080 System Evaluation Mix
Rice  flour  (amylose,  high  level) Rice flour (amylose, high level)
Abrasive  for  crystal-polishing  kit Abrasive for crystal-polishing kit
EPA  VOC  Mix  2 EPA VOC Mix 2
EPA  610-N  PAH  Kit EPA 610-N PAH Kit
EPA  524  Revision  4  Calibration  Kit EPA 524 Revision 4 Calibration Kit
EPA  606-M  Phthalate  Esters  Mix EPA 606-M Phthalate Esters Mix
Quick  Press  hand  press  only Quick Press hand press only
Brush  for  crystal-polishing  kit Brush for crystal-polishing kit
GPC  Calibration  Mix  A GPC Calibration Mix A
Human  serum  (high  creatinine) Human serum (high creatinine)
Ground  water  (Br,  low  level) Ground water (Br, low level)
EPA  624  Calibration  Mix  A  (w/o  gases) EPA 624 Calibration Mix A (w/o gases)
EPA  Appendix  IX  Volatiles  Calibration  Mix EPA Appendix IX Volatiles Calibration Mix
Calcium  ionophore  II  -  membrane  A Calcium ionophore II - membrane A
Electrode  Connecting  Wire  with  Lemo/BNC-Connector Electrode Connecting Wire with Lemo/BNC-Connector
Septum  regulator  for  syringe  samples  for  20  L Septum regulator for syringe samples for 20 L
Polyethylene  glycol  Standard  ReadyCal  Set  Mp  102-40μ000 Polyethylene glycol Standard ReadyCal Set Mp 102-40μ000
Ruthenium  ICP/DCP  standard  solution Ruthenium ICP/DCP standard solution Ru
EPA  TCLP  Pesticide  Mix EPA TCLP Pesticide Mix
EPA  8080  Spiking  Mix EPA 8080 Spiking Mix
TLC  plate  rack TLC plate rack
Wheat  flour  (deoxynivalenol,  blank) Wheat flour (deoxynivalenol, blank)
Silver  sulfate  6,6  g/l  in  sulfuric  acid Silver sulfate 6,6 g/l in sulfuric acid
Gas  oil  (0.363  %  S) Gas oil (0.363 % S)
EPA  525  Fortification  Solution  A EPA 525 Fortification Solution A
MODEL  24  SCOTTY(R)  IV  REGUL.  &  GAUGE  (CGA  165) MODEL 24 SCOTTY(R) IV REGUL. & GAUGE (CGA 165)
EPA  8270D  Base-Neutral  Mix EPA 8270D Base-Neutral Mix
DRO  Calibration  Mix DRO Calibration Mix
EPA  624  Purgeable  Calibration  Mix  w/o  Gases,  includes  2-CEVE EPA 624 Purgeable Calibration Mix w/o Gases, includes 2-CEVE
Sewage  sludge  (industrial  origin)  (trace  elements) Sewage sludge (industrial origin) (trace elements)
Gas  oil  (0.502  %  S) Gas oil (0.502 % S)
EPA  8260  Calibration  Mix  3 EPA 8260 Calibration Mix 3
EPA  8260  Ketones  Mix EPA 8260 Ketones Mix
(Z)-2-Hexadecenoic acid methyl ester (Z)-2-Hexadecenoic acid methyl ester 2825-80-1 C17H32O2
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