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Analytical Chemistry

Analytical chemistry is the subject for the method and basic principle of studying and identifying of the composition, status, structure of matter as well as determination of related content. It is an important branch of chemistry subject. Analytical chemistry plays an important role in not only its own development but also in various fields related to the chemistry. We can say that all the practice of any human activity involving chemical phenomena is inseparable from analytical chemistry. Now, people have developed various kinds of different analytical methods, which can be classified based on an analysis task, analysis object, the basis of the analysis, requirement of the analysis and sample dosage.

According to the analysis tasks, it can be divided into qualitative analysis, quantitative analysis and structural analysis. Task of qualitative analysis is to identify the elements, radicals, functional groups or compounds that constituting the substances; the task of the quantitative analysis is to determine the content of the related components in the sample; the task of structural analysis is to study the molecular structure or crystal structure of the material.

(1) According to the analysis objects, it can be divided into organic and inorganic analysis; the object for the inorganic analysis is inorganic substance; the object of organic analysis is organic substance. In the inorganic analysis, it is generally required to determine what elements, ions, radicals or compounds that constitutes the sample and measure the percentage of each component; and sometimes it is also necessary for determination of the crystal structure; in the organic analysis, it not only requires the identification of the constituent elements, but also, more importantly, should do the structure analysis and functional group analysis.
(2) According to whether the analysis is based on the physical properties or chemical properties of the substance, it can be divided into instrumental analysis and chemical analysis. Depending on the specific requirements, it can be divided into routine analysis, rapid analysis and arbitration Analysis. Routine analysis refers to the general daily laboratory production analysis, also known as conventional analysis; rapid analysis is a kind of routine analysis and is mainly applied to the control of the production process, demanding the report of the results in the shortest possible time with the error generally being allowed to be greater; arbitration analysis is needed when there is controversy in the analysis results from different institute, demanding related department to conduct accurate analysis using specific method in order to determine the accuracy of the results of the original analysis.
(3) According to the amount of the sample, it can be generally divided into constant (> 0.1g), semi-micro (0.01 ~ 0.1g) and trace (1 ~ 10mg) analysis.
(4) In the inorganic qualitative chemical analysis, people generally apply semi-micro method while people generally apply constant analysis in the quantitative chemical analysis. According to the relative amounts of the analyzed components contained in the sample, it is also roughly divided into constant component analysis (> 1%), minor component analysis (0.01 to 1%) and trace components analysis (<0.01%). For the analysis of some trace amount of components contained in some kinds of complicated mixture and some substances, it is necessary to perform separation and enrichment. This produces a series of separation techniques, such as extraction, distillation, ion exchange, chromatography, sedimentation and flotation separation, these chemical separation techniques are an integral part of the analysis.

Environmental Analytical Chemistry
Environmental Analytical Chemistry is briefly referred to environmental analysis. It is a kind of subject to study the types, components of pollutants in the environment as well as how to perform qualitative and quantitative analysis on the chemical contaminants in the environment. It is a branch of environmental chemistry.

Environmental analytical chemistry emerged, developed and improved during the process of solving environmental problems. In 1950s, the public nuisance disease occurred in Japan had alerted the whole world. In order to find the cause of public nuisance disease, after experiencing as long as 11 years, later, the chemists of environmental analysis had applied light spectrum and identified that the river in Itai-itai disease area contained harmful elements such as lead, cadmium, arsenic and so on. Further by means of tracking element analysis of the soil and food in the disease area, people had found high lead and cadmium content. Later, people had further conducted spectral quantitative analysis on the body and bone of the patients in the disease area and found that the bone ashes contained alarmingly high content of zinc, lead and cadmium. To determine the causative agent, people further incorporated zinc, lead and cadmium into the food for feeding animals and conduct trace elemental analysis for animals and confirmed the serious harm of cadmium on the bone, revealing the cause of the Itai-itai disease. The development of modern science, especially the development of modern chemistry, physics, mathematics, electronics, biology, as well as the emergence of accurate, reliable, sensitive, selective, rapid, simple environmental pollution analysis technology and automation equipment, has been resulting in the maturation of environmental analytical chemistry. Environmental analytical chemistry now has penetrated into all areas of the entire environmental science subject. It is the most effective means of access to environmental information quality.
The objects of the environmental analytical chemistry research are quite complicated, including air, water, soil, sediment, minerals, waste, animals, plants, food, and human tissue. The content of chemical elements or compound to be determined in the environmental analytic chemistry is very low, with the absolute content being within the level of 10-6 to 10-12 grams.


The analysis technology in the environmental analytical chemistry is developing towards the direction of continuous automation, computerization and joint combination of various methods and instruments. Currently applied automatic analysis methods include colorimetric analysis, ion selective electrode, x-ray fluorescence spectroscopy, atomic absorption spectroscopy, polarography, gas chromatography, liquid chromatography and flow injection analysis. Laser, as the light source of analytical chemistry technique, has also been applied. Since the laser analysis has properties of high resolution, high sensitivity, long-range and short-term, the laser technology will play a pivotal role in the development of environmental analytical chemistry.

With the deepened development of environmental science, environmental analytical chemistry is often demanded for trace levels and ultra-trace-level detection and analysis, therefore, high sensitivity. Thus study of analysis methods of high sensitivity, good selectivity, rapid trace and ultra trace will become the major development direction for environmental analysis in the near future.

Qualitative Analysis of Chemistry
Qualitative analytic chemistry is the subject to identify the chemical elements and atoms groups contained in the sample. It is a branch subject of the analysis chemistry. Its purpose is to ascertain the chemical composition of the research object (specimen).
The major research content of the qualitative analytic chemistry includes:

1 the tested samples were analyzed separately. Namely take part of the sample and use exclusive reaction to detect a desire detection component.
2 systematic analysis of the samples. This means successively apply a few selective reactions for gradual separation of the ions followed by separation of each group until separating to only one substance and finally apply confirming reaction to ascertain the existence of this substance. The most famous cation system analysis method is H2S system. In recent years, due to the use of advanced equipment, qualitative analysis has also rapidly developed together with multivariate analysis and has also become an important direction for analytical chemistry.

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Structure Chemical Name CAS MF
AQUANAL -professional Hydrazine Powder
		
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EPA 8270 Base Neutral Calibration Mix 2
		
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AQUANAL-professional ortho-Phosphate tube test
		
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Model 226 Single-Stage Regulator, CGA-170, (for SCOTTY 74L cylinder)
		
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Block heater (without block), 220V
		
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Multielement standard solution 4 for ICP
		
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Agate vial and ball pestle for analog Wig-L-Bug grinder/mixer
		
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AQUANAL-professional Vario H Phosphate hydr.
		
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Leaded brass
		
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1,5-Pentanediyl-bis(3-benzylimidazolium) difluoride solution
		
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Galvanizing Alloy
		
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1,3,5-Tris[(tripropylphosphonium)methyl]benzene trifluoride solution
		
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Polystyrene standard set Mp 400-1′800′000
		
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Titanium (impurities)
		
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Real Crystal IR sample cards
		
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chromatography papers chromatography papers
Titanium Standard for AAS
		
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Replacement Viton O-rings for plunger Z506737
		
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Iron, AAS standard solution,  Fe 50g/l Iron, AAS standard solution, Fe 50g/l Fe
Volatile  Organic  Compounds  Mix  6 Volatile Organic Compounds Mix 6
N,Nμ-(Methylenediphenylene)bis{4-(2-pyridinyl)-1-piperazinecarboxamide}  (derivative  of  4,4μ-MDIP) N,Nμ-(Methylenediphenylene)bis{4-(2-pyridinyl)-1-piperazinecarboxamide} (derivative of 4,4μ-MDIP)
EPA  8080  Pesticides  Mix EPA 8080 Pesticides Mix
EPA  Purgeable  A EPA Purgeable A
EPA  Phthalate  Esters  Mix EPA Phthalate Esters Mix
EPA  8040A  Phenol  Calibration  Mix EPA 8040A Phenol Calibration Mix
Margarine  (vitamins) Margarine (vitamins)
EPA  VOC  Mix  7 EPA VOC Mix 7
Human  serum  (high  progesterone) Human serum (high progesterone)
EPA  524  Surrogate  Standard  Mix EPA 524 Surrogate Standard Mix
Flow  adapter  for  jacketed  LC  columns Flow adapter for jacketed LC columns
Human  serum  (low  creatinine) Human serum (low creatinine)
262-NP,  4-(1,1,5-Trimethylhexyl)phenol 262-NP, 4-(1,1,5-Trimethylhexyl)phenol 521947-27-3 C15H24O
Bovine  urine  (clenbuterol,  salbutamol  low  level) Bovine urine (clenbuterol, salbutamol low level)
EPA  8270  Supplemental  Mix  3 EPA 8270 Supplemental Mix 3
GC  Volatiles  Mix  1 GC Volatiles Mix 1
EPA  502/524  Volatiles  Organic  Calibration  Mix  A  (without  gases) EPA 502/524 Volatiles Organic Calibration Mix A (without gases)
Wastewater  (trace  elements) Wastewater (trace elements)
Boron  Standard  for  ICP Boron Standard for ICP BH3
EPA  VOC  Mix  1 EPA VOC Mix 1
Calcium  ICP/DCP  standard  solution Calcium ICP/DCP standard solution Ca
EPA  VOC  Mix  4 EPA VOC Mix 4
EPA  8040A  Phenols  Mix EPA 8040A Phenols Mix
Ph  Eur  5.0  Calibration  Mix  for  GC Ph Eur 5.0 Calibration Mix for GC
Oxygenates  Mix  1 Oxygenates Mix 1
Ground  water  (trace  elements,  low  level) Ground water (trace elements, low level)
Calcium  matrix  modifier  solution Calcium matrix modifier solution Ca
2-(Bromomethyl)tetra-2H-pyran 2-(Bromomethyl)tetra-2H-pyran
2-Diphenylacetyl-3-(cyclohexyl-hydrazono)indan-1-one 2-Diphenylacetyl-3-(cyclohexyl-hydrazono)indan-1-one 108041-11-8 C29H26N2O2
2-Methyl-3-amino-5-nitrobenzamide 2-Methyl-3-amino-5-nitrobenzamide 3572-44-9 C8H9N3O3
m-Nitrotoluene Standard m-Nitrotoluene Standard C7H7NO2
DIMETHYL HEXACOSANEDIOATE DIMETHYL HEXACOSANEDIOATE 86797-43-5 C28H54O4
2-{2-[7-(DiethylaMino)-2-oxo-2H-1-benzopyran-3-yl]ethenyl}-1,3,3-triMethyl-3H-indoliuM iodide 2-{2-[7-(DiethylaMino)-2-oxo-2H-1-benzopyran-3-yl]ethenyl}-1,3,3-triMethyl-3H-indoliuM iodide 1352626-59-5 C26H29IN2O2
AQUANAL-plus zinc (Zn) 0.02-0.2 mg/L
		
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α-Alumina (0.10 m2/g) (nitrogen BET specific surface area)
		
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MethylEicosatrienoate(11c,14c,17c) MethylEicosatrienoate(11c,14c,17c)
MethylTransvaccenate(11tr) MethylTransvaccenate(11tr)
HYDRANALCHLOROFORM HYDRANALCHLOROFORM
Naratriptan Resolution Mixture Naratriptan Resolution Mixture
96946-42-8 96946-42-8 96946-42-8
L-Cefadroxil L-Cefadroxil 144790-28-3 C16H17N3O5S
DODECANOIC ACID-1,2-13C2 DODECANOIC ACID-1,2-13C2 287111-19-7 C12H24O2
potassium tetraiodobismuthate potassium tetraiodobismuthate 39775-75-2 BiH4I4K
N,N'-desoxycarbadox N,N'-desoxycarbadox 55456-55-8 C11H10N4O2
OCTANOIC ACID-13C8 OCTANOIC ACID-13C8 C8H16O2
METHYL 3-HYDROXYTRIDECANOATE METHYL 3-HYDROXYTRIDECANOATE 150024-70-7 C14H28O3
2,4-dinitro-N-(octylideneamino)aniline 2,4-dinitro-N-(octylideneamino)aniline 1726-77-8 C14H20N4O4
CESIUM CHLORIDE LANTHANUM CHLORIDE BUFFER CESIUM CHLORIDE LANTHANUM CHLORIDE BUFFER Cl4CsLa
Petroleum  Refinery  Reformate Petroleum Refinery Reformate
MISA  Group  17  Non-Halogen  Organic  Mix MISA Group 17 Non-Halogen Organic Mix
Dietary  Fiber,  Total,  Assay  Control  Kit Dietary Fiber, Total, Assay Control Kit
Aluminum  ICP/DCP  standard  solution Aluminum ICP/DCP standard solution Al
Chlorine  37Cl  (certified  for  isotope  abundance  ratio) Chlorine 37Cl (certified for isotope abundance ratio)
Olefins  Mix Olefins Mix
Ethylene  in  helium Ethylene in helium
Acid  Herbicide  Spiking  Mix  2 Acid Herbicide Spiking Mix 2
Artificial  foodstuff  (Fructose,  Sucrose,  Lactose  and  Starch/glucose) Artificial foodstuff (Fructose, Sucrose, Lactose and Starch/glucose)
EPA  8270  Acids  Surrogate  Spike  Mix EPA 8270 Acids Surrogate Spike Mix
Creatinine  (interfering  substances) Creatinine (interfering substances) C4H7N3O
Cadmium-111Cd  solution Cadmium-111Cd solution Cd
Pharmaceutical  glass  containers  (Alkali  leaching  and  release) Pharmaceutical glass containers (Alkali leaching and release)
HPLC  Isocratic  Systems  Diagnostics  Mix HPLC Isocratic Systems Diagnostics Mix
Asbestos  fibres  in  lung  tissue  (low  content  of  amosite  +  crocidolite) Asbestos fibres in lung tissue (low content of amosite + crocidolite)
Oxygen  in  nitrogen,  6  % Oxygen in nitrogen, 6 %
Defatted  peanut  meal  (aflatoxin  B1,  high  level) Defatted peanut meal (aflatoxin B1, high level)
Lithium  carbonate-7Li Lithium carbonate-7Li 7Li2CO3
Poly  TLC  Plates:  Cellulose  with  Fluorescence,  TLC-PET  foils  cellulose Poly TLC Plates: Cellulose with Fluorescence, TLC-PET foils cellulose
EPA  8081  Pesticide  Standard  Mix EPA 8081 Pesticide Standard Mix
EPA  8015  Nonhalogenated  Volatile  Organics  Mix EPA 8015 Nonhalogenated Volatile Organics Mix
Road  dust  (trace  elements) Road dust (trace elements)
Beer  (EtOH,  low  level) Beer (EtOH, low level)
EPA  CLP  Semivolatile  Kit EPA CLP Semivolatile Kit
Aluminum  oxide  on  TLC-plates Aluminum oxide on TLC-plates Al2O3
Resin  bonded  glass  fibreboard  (thermal  conductivity) Resin bonded glass fibreboard (thermal conductivity)
MISA  Group  23  Chlorinated  Hydrocarbon  Mix MISA Group 23 Chlorinated Hydrocarbon Mix
EPA  8150  Herbicide  Methyl  Derivatives  Mix EPA 8150 Herbicide Methyl Derivatives Mix
Sodium  ionophore  I  -  membrane  A Sodium ionophore I - membrane A
8270  Add-On  Mix  2 8270 Add-On Mix 2
Palladium  ICP/DCP  standard  solution Palladium ICP/DCP standard solution Pd
S-Metolachlor CGA 357704 S-Metolachlor CGA 357704 1217465-10-5 C14H17NO5
Rosiglitazone Related Compound A (25 mg) ((5Z)-5-{[4-({2-[methyl(2-pyridinyl)amino]ethyl}oxy)phenyl]methylidene}-1,3-thiazolidine-2,4-dione) Rosiglitazone Related Compound A (25 mg) ((5Z)-5-{[4-({2-[methyl(2-pyridinyl)amino]ethyl}oxy)phenyl]methylidene}-1,3-thiazolidine-2,4-dione) 160596-25-8 C18H17N3O3S
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