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1-Methoxy-2,4-dinitrobenzene

1-Methoxy-2,4-dinitrobenzene ??? ???
?? ??:
119-27-7
???:
1-Methoxy-2,4-dinitrobenzene
???(??):
Dinitroanisole;-Dinitroanisole;2,4-Nitroanisole;2,4-Dinitroanisol;2,4-DINITROANISOLE;2,4-dimitroanisole;2,4-dinitro-anisol;alpha-Dinitroanisole;2,4-Dinitroanisole99%;Anisole, 2,4-dinitro-
CBNumber:
CB5852910
???:
C7H6N2O5
??? ??:
198.13
MOL ??:
119-27-7.mol

1-Methoxy-2,4-dinitrobenzene ??

???
94-96 °C(lit.)
?? ?
207°C/12mm
??
1.34 g/mL at 25 °C(lit.)
???
0.001Pa at 25℃
???
1.5460 (estimate)
???
207°C/12mm
???
??? ???? ?? ???; ?? ???. ???, 155mg/L 15°C. ?? ????? & ???.
BRN
1881474
LogP
1.58 at 25℃
CAS ??????
119-27-7(CAS DataBase Reference)
NIST
Benzene, 1-methoxy-2,4-dinitro-(119-27-7)
EPA
2,4-Dinitroanisole (119-27-7)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn
?? ???? ?? 20/21/22-40-22
????? 7/8-22-36/37/39
WGK ?? 3
RTECS ?? DA5250000
TSCA Yes
?? ?? 6.1
?? rat,LDLo,oral,100mg/kg (100mg/kg),National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. Vol. 5, Pg. 16, 1953.
????(GHS): GHS hazard pictograms
?? ?:
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H301 ??? ??? ?? ?? ?? - ?? ?? 3 ?? GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P321 (…) ??? ???.
P405 ???? ?????.
NFPA 704
0
3 0

1-Methoxy-2,4-dinitrobenzene MSDS


1-Methoxy-2,4-dinitrobenzene

1-Methoxy-2,4-dinitrobenzene C??? ??, ??, ??

??? ??

yellow crystals or crystalline powder

??

It can be used as a dye ingredient. It is one of the insensitive nitroaromatic ingredients increasingly used as a replacement for 2,4,6-trinitrotoluene (TNT) in munitions.

?? ??

2,4-Dinitrochlorobenzene is treated with methanolic sodium hydroxide in a process similar to that described for 4-nitroanisole. 2,4-Dinitrophenetole [610-54-8] is similarly manufactured by using ethanol.

??

ChEBI: A member of the class of dinitroanisoles that is 2-nitroanisole in which the hydrogen para to the methoxy group is replaced by a second nitro group.

Safety Profile

Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS of AROMATIC HYDROCARBONS and NITRATES.

Purification Methods

Purify the anisole by repeated crystallisation from EtOH, MeOH or H2O and dry it in a vacuum desiccator over P2O5. The naphthalene complex has m 69o (from EtOH). [Beilstein 6 III 869, 6 IV 1385.

1-Methoxy-2,4-dinitrobenzene ?? ?? ? ???

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1-Methoxy-2,4-dinitrobenzene ?? ??:

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