ChemicalBook >?? ???? >(R,R)-I-PR-???
(R,R)-I-PR-???
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(R,R)-I-PR-??? ??
- ???
- 40°C
- ??
- +85° (c 1, hexane)
- ?? ?
- 502.0±20.0 °C(Predicted)
- ???
- n20/D 1.5701
- ???
- >110°(230°F)
- ?? ??
- under inert gas (nitrogen or Argon) at 2-8°C
- ??? ??
- ?? ??
- ??
- ???
- ??? (Optical Rotation)
- [α]20/D +103°, c = 1 in chloroform
- ???
- ?? ???.
- ??
- Air Sensitive
- InChI
- InChI=1S/C26H44P2/c1-17(2)21-13-14-22(18(3)4)27(21)25-11-9-10-12-26(25)28-23(19(5)6)15-16-24(28)20(7)8/h9-12,17-24H,13-16H2,1-8H3/t21-,22-,23-,24-/m1/s1
- InChIKey
- RBVGOQHQBUPSGX-MOUTVQLLSA-N
- SMILES
- C1(P2[C@@H](C(C)C)CC[C@@H]2C(C)C)=CC=CC=C1P1[C@@H](C(C)C)CC[C@@H]1C(C)C
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- ?? ? ???? ?? (GHS)
| ?? ???? ?? | 36/37/38 | ||
|---|---|---|---|
| ????? | 26-36/37/39 | ||
| WGK ?? | 3 |
(R,R)-I-PR-??? C??? ??, ??, ??
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It is used as ligands like DuPhos and BPE ligands and are highly efficient privileged ligands.?? ??
Optical rotation devation ± 13(R,R)-I-PR-??? ?? ?? ? ???
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(R,R)-I-PR-??? ?? ??
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| ??? | ?? | ??? | ?? | ?? ? | ?? |
|---|---|---|---|---|---|
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(R,R)-I-PR-??? ?? ??:
(S,S)-I-PR-DUPHOS-RH
(-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.98%(S,S)-i-Pr-DUPHOS-Rh
(S,S)-I-PR-DUPHOS,(-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene,98+%(S,S)-i-Pr-DUPHOS
(R,R)-I-PR-DUPHOS-RH,(+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene)1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.98%(R,R)-i-Pr-DUPHOS-Rh
DI-I-BUTYLPHOSPHINE
(+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE
(+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE
(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene