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ChemicalBook >> CAS DataBase List >>4-CHLORO-2-METHYLQUINOLINE

4-CHLORO-2-METHYLQUINOLINE

CAS No.
4295-06-1
Chemical Name:
4-CHLORO-2-METHYLQUINOLINE
Synonyms
AKOS BBS-00000956;4-CHLOROQUINALDINE;TIMTEC-BB SBB005362;Quinaldine, 4-chloro-;4-Chloroquinaldine 99%;4-CHLORO-2-METHYLQUINOLINE;2-Methyl-4-chloroquinoline;Quinoline, 4-chloro-2-methyl-;4-Chloro-2-methylquinoline>JR-8354, 4-Chloroquinaldine, 97%
CBNumber:
CB4286158
Molecular Formula:
C10H8ClN
Molecular Weight:
177.63
MDL Number:
MFCD00006757
MOL File:
4295-06-1.mol
MSDS File:
SDS
Last updated:2025-07-24 18:13:47

4-CHLORO-2-METHYLQUINOLINE Properties

Melting point 39 °C
Boiling point 269-270 °C (lit.)
Density 0.881 g/mL at 25 °C (lit.)
refractive index n20/D 1.622(lit.)
Flash point >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka 4.40±0.50(Predicted)
form powder to lump to clear liquid
color White or Colorless to Yellow
Water Solubility Slightly soluble in water.
BRN 3522
InChI InChI=1S/C10H8ClN/c1-7-6-9(11)8-4-2-3-5-10(8)12-7/h2-6H,1H3
InChIKey HQAIROMRVBVWSK-UHFFFAOYSA-N
SMILES N1C2C(=CC=CC=2)C(Cl)=CC=1C
CAS DataBase Reference 4295-06-1(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
HS Code  2933499090
NFPA 704
0
2 0

4-CHLORO-2-METHYLQUINOLINE price More Price(38)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 150231 4-Chloroquinaldine 99% 4295-06-1 5g $118 2023-01-07 Buy
Sigma-Aldrich 150231 4-Chloroquinaldine 99% 4295-06-1 25g $565 2023-01-07 Buy
TCI Chemical C2901 4-Chloro-2-methylquinoline >98.0%(GC) 4295-06-1 5g $162 2025-07-31 Buy
TRC C895623 4-?Chloroquinaldine 4295-06-1 250mg $45 2021-12-16 Buy
Biosynth Carbosynth FC75575 4-Chloro-2-methylquinoline 4295-06-1 1g $65 2021-12-16 Buy
Product number Packaging Price Buy
150231 5g $118 Buy
150231 25g $565 Buy
C2901 5g $162 Buy
C895623 250mg $45 Buy
FC75575 1g $65 Buy

4-CHLORO-2-METHYLQUINOLINE Chemical Properties,Uses,Production

Uses

4-Chloroquinaldine is used in the preparation of 4-phenyl-hydrazinoquinaldine

Synthesis

4-Hydroxy-2-methylquinoline

607-67-0

4-CHLORO-2-METHYLQUINOLINE

4295-06-1

General procedure: 4-hydroxy-2-methylquinoline (5a-c) was added to POCl3 and the reaction mixture was heated to reflux for 12 hours. Upon completion of the reaction, the excess POCl3 was removed by distillation under reduced pressure. the residue was washed once and twice each with CHCl3 and toluene sequentially. The solid obtained was dissolved in CH2Cl2 and triethylamine was added dropwise until the pH of the aqueous wash solution was greater than 10. Finally, the reaction mixture was filtered to afford the target products 2-methyl-4-chloroquinoline (6a-c).

References

[1] European Journal of Medicinal Chemistry, 2017, vol. 138, p. 1114 - 1125
[2] Patent: US2008/171765, 2008, A1. Location in patent: Page/Page column 19-20
[3] Australian Journal of Chemistry, 2003, vol. 56, # 1, p. 39 - 44
[4] Letters in Drug Design and Discovery, 2018, vol. 15, # 9, p. 937 - 944
[5] Patent: WO2018/178277, 2018, A1. Location in patent: Paragraph 00114

607-67-0
4295-06-1
Synthesis of 4-CHLORO-2-METHYLQUINOLINE from 4-Hydroxy-2-methylquinoline

4-CHLORO-2-METHYLQUINOLINE Suppliers

Global( 133)Suppliers
Supplier Tel Email Country ProdList Advantage
Hubei xin bonus chemical co. LTD 		86-13657291602 linda@hubeijusheng.com CHINA 22963 58
Alchem Pharmtech,Inc. 		8485655694 sales@alchempharmtech.com United States 63687 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49733 58
Hubei Ipure Biology Co., Ltd 		+8613367258412 ada@ipurechemical.com China 10244 58
Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
HONG KONG IPURE BIOLOGY CO.,LIMITED 		86 18062405514 18062405514 ada@ipurechemical.com CHINA 3461 58
Dideu Industries Group Limited 		+86-29-89586680 +86-15129568250 1026@dideu.com China 22058 58
Dayang Chem (Hangzhou) Co.,Ltd. 		+86-0571-88938639 +8617705817739 info@dycnchem.com China 52846 58
Labnetwork lnc. 		+86-27-50766799 +8618062016861 contact@labnetwork.com China 19987 58
Nanjing Hengbei Chemicals Co., Ltd. 		+86-25-58393656 sales@hengbeichem.cn China 6854 58

View Lastest Price from 4-CHLORO-2-METHYLQUINOLINE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-CHLORO-2-METHYLQUINOLINE pictures 2022-03-09 4-CHLORO-2-METHYLQUINOLINE
4295-06-1
 US $1.10 / g 1g 99.00% 100 Tons Dideu Industries Group Limited
TIMTEC-BB SBB005362 AKOS BBS-00000956 4-CHLOROQUINALDINE 4-CHLORO-2-METHYLQUINOLINE Quinaldine, 4-chloro- Quinoline, 4-chloro-2-methyl- 2-Methyl-4-chloroquinoline 4-Chloroquinaldine 99% JR-8354, 4-Chloroquinaldine, 97% 4-Chloro-2-methylquinoline> 4-CHLORO-2-METHYLQUINOLINE ISO 9001：2015 REACH 4295-06-1 Building Blocks Quinaldines Halogenated Heterocycles Heterocyclic Building Blocks Quinolines, Isoquinolines & Quinoxalines QuinaldinesHeterocyclic Building Blocks Building Blocks Halogenated Heterocycles Heterocyclic Building Blocks Quinaldines Quinolines Halides Quinolines, Isoquinolines & Quinoxalines