1,1'-Bis(diphenylphosphino)ferrocene
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- CAS-Nr.
- 12150-46-8
- Englisch Name:
- 1,1'-Bis(diphenylphosphino)ferrocene
- Synonyma:
- DPPF;Bis(diphenylphosphino)ferrocene;1,1'-FERROCENEDIYL-BIS(DIPHENYLPHOSPHINE);98% DPPF;DPPF ChemBeads;1,1'-Bis(diphenylpho;Terazolamide Impurity 83;Zirconium ionophore I
;phosphino)ferrocene (DPPF);1,1-(twophenylphosphine)Er Maotie
- CBNumber:
- CB2746748
- Summenformel:
- C34H28FeP210*
- Molgewicht:
- 554.38
- MOL-Datei:
- 12150-46-8.mol
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1,1'-Bis(diphenylphosphino)ferrocene Eigenschaften
- Schmelzpunkt:
- 181-182 °C (dec.)(lit.)
- storage temp.
- 2-8°C
- L?slichkeit
- Chloroform, Ethyl Acetate
- Aggregatzustand
- crystal
- Farbe
- yellow to orange
- Wasserl?slichkeit
- Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.
- Sensitive
- Air Sensitive
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- Stabilit?t:
- Stable. Incompatible with strong oxidizing agents.
- InChI
- InChI=1S/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;
- InChIKey
- HPXNTHKXCYMIJL-UHFFFAOYSA-N
- SMILES
- P(C1C=CC=CC=1)(C1=CC=CC=C1)[C]1[CH][CH][CH][CH]1.P(C1=CC=CC=C1)(C1=CC=CC=C1)[C]1[CH][CH][CH][CH]1.[Fe] |^1:13,14,15,16,17,31,32,33,34,35|
- CAS Datenbank
- 12150-46-8(CAS DataBase Reference)
- NIST chemische Informationen
1,1'-Bis(diphenylphosphino)ferrocene Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R25:Giftig beim Verschlucken.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R20/21/22:Gesundheitssch?dlich beim Einatmen,Verschlucken und Berührung mit der Haut.
S-S?tze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
1,1'-Bis(diphenylphosphino)ferrocene is deep yellow crystalline powder
Verwenden
1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.
Allgemeine Beschreibung
Novel functionalized furan derivatives were prepared via Pd-phosphine sequential C-C and C-O bond formation.
l?uterung methode
Wash it with distilled H2O and dry it in a vacuum. Dissolve it in ca 5 parts of hot dioxane and cool to give orange crystals m 181-183o. Recrystallisation from *C6H6/heptane (1:2) gives a product with m 183-184o. [Bishop et al. J Organomet Chem 27 241 1971.]
1,1'-Bis(diphenylphosphino)ferrocene Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Ferrocen
N,N,N',N'-Tetramethylethylendiamin
3a,4,7,7a-Tetrahydro-4,7-methan-1H-inden
Eisendichlorid
Chlordiphenylphosphin
Tetrahydrofuran
Ethylacetat
Dichlormethan
Natriumhydroxid
Butyllithium
Lithium, [1-(diphenylphosphino)-2,4-cyclopentadien-1-yl]-
Diphenylphosphinoferrocene
1,1'-bis(diphenylphosphinyl)-Ferrocene
4,4'-Bis(t-butyl)-1,1',2,2'-tetrakis(diphenylphosphino)ferrocene, 98% HiersoPHOS-5
Dimethylphenylphosphin
Natriumthiocyanat
Natriumdiethyldithiocarbamat
Phenyllithium
Downstream Produkte
1,1'-Bis(diphenylphosphino)ferrocene Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 495)Lieferanten
12150-46-8()Verwandte Suche:
- 1,1''-BIS(DIPHENYLPHOSPHINO)ERROCENE
- 1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE (DPPF)
- DPPF/1,1''-BIS(DIPHENYLPHOSPHINO) FERROCENE
- 1,1'-Bis(diphenylphosphiNA)ferrocene
- DPPF, (Ferrocene-1,1'-diyl)bis(diphenylphosphine)
- 1,1-(twophenylphosphine)Er Maotie
- 1,1'-FERROCENEBIS(DIPHENYLPHOSPHINE)
- 1,1'-bis(diphenyphosphino)ferrocene
- 1,1'-bis(diphenyphosphino)ferrocene(dppf)
- 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE, 97 %
- 1,1'-Bis(diphenylphosphino)ferrocene,99%DPPF
- 1,1'- double(twophenylphosphine)Er Maotie
- 1,1'-Bis(diphenylphosphino)ferrocene 97%
- 1,1'-Bis(diphenylphosphino)ferrocene (DPPF), 95+%
- 1,1'-Bis(diphenylphosphino)ferrocene
1,1'-Ferrocenebis(diphenylphosphine)
- 1,1'-Bis(diphenylphosphino)ferrocene,98% DPPF
- bis(2-(diphenylphosphino)cyclopenta-2,4-dien-1-yl)iron
- dppf
1,1'-Ferrocenebis(diphenylphosphine)
1,1'-Ferrocenediyl-bis(diphenylphosphine)
- Zirconium ionophore I
- 1,1'-Bis(diphenylphosphino) ferrocene, Catalyst Grade
- 1,1'-Bis(diphenylphosphino)ferrocene, C 73.4%, H 5.2%
- 1,1μ-Ferrocenebis(diphenylphosphine), 1,1μ-Ferrocenediyl-bis(diphenylphosphine)
- 1,1''-BIS-(DIPHENYLPHOSPHINO)-FEROCENE
- 1,1'-Bis(diphenylphosphino)ferrocene,98%
- 1,1'-Bis(diphenylphosphino)ferrocene,99%
- 1,1'-Bis(diphenylpho
- 1'-Bis(diphenylphosphino)ferrocene
- 1,1'-bis(diphenylphosphine) Ferrocene
- 98% DPPF
- 1,1'-Ferrocendiylbis(diphenylphosphine)
- Cyclopentadienyldiphenylphosphine
- 1,1'-Ferrocenebis(diphenylphosphine)
dppf
- phosphino)ferrocene (DPPF)
- 1,1'-Bis(diphenylphosphino)ferrocene>
- 1,1'-Bis(diphenylphosphino)ferrocene ISO 9001：2015 REACH
- cyclopenta-2,4-dien-1-yl(diphenyl)phosphane(1:2)
- DPPF (1,1-Bis(Diphenylphosphino)Ferrocene) extrapure, 98%
- Ferrocene,1,1'-bis(diphenylphosphino)-
- DPPF
- 1,1'-FERROCENEDIYL-BIS(DIPHENYLPHOSPHINE)
- Bis(diphenylphosphino)ferrocene
- 1,1'-Bis(diphenylphosphino)ferrocene,
94%
- 1,1'-Bis(diphenylphosphino)ferrocene
- 1,1'- bis (diphenylphosphine) ferrocene
- 1,1'-Bis(diphenylphosphino)ferrocene (Dppf)
- Ferrocene, 1,1'-bis(diphenylphosphino)-
- Terazolamide Impurity 83
- 1,1'-Bis(diphenylphosphino)ferrocene,
94%
- DPPF ChemBeads
- 1,1′-Bis(diphenylphosphino)ferrocene, CAS 12150-46-8
- 1,1'-Bis(diphenylphosphino)ferrocene
- 12150-46-8
- C34H28FeP2
- C35H30Cl2FeP2
- C6H52PC5H4FeC5H4PC6H52
- Polydentate Phosphine Ligands
- Phosphorus Compounds
- Fe (Iron) Compounds
