| Identification | More | [Name]
Diisopropyl succinate | [CAS]
924-88-9 | [Synonyms]
BUTANEDIOIC ACID, BIS(1-METHYL-ETHYL) ESTER
DIISOPROPYL SUCCINATE
DIPS
SUCCINIC ACID DIISOPROPYL ESTER
Bis(1-methylethyl)butanedioate | [EINECS(EC#)]
213-110-0 | [Molecular Formula]
C10H18O4 | [MDL Number]
MFCD00059360 | [Molecular Weight]
202.25 | [MOL File]
924-88-9.mol |
| Safety Data | Back Directory | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [HS Code ]
2917.19.1700 |
| Hazard Information | Back Directory | [Uses]
Diisopropyl Succinate is used in preparation of Heterocyclic Pyrrolopyrrole Diketone quaternary Ammonium Salt as Copper electroplating leveling agent. | [Synthesis]
In a typical reaction, butanedioic acid (1 mol), isopropanol (1.5-2 mol) and AMA 2:3 (332 g, 0.6 mol) were mixed in a reaction glass tube equipped with a screw cap and a magnetic stirrer until a homogeneous wet mixture was formed. The reaction mixture was placed in a microwave reactor (Anton Parr Monowave 300) and irradiated at 80 °C for 8 min or at 120 °C for 20 min. Upon completion of the reaction, the mixture was cooled, diluted with dichloromethane (41 mL), filtered by gravity and the filtrate was washed with dichloromethane. Subsequently, the filtrate was washed sequentially with saturated sodium carbonate solution (Na2CO3) and water. The organic layer was separated, dried with anhydrous sodium sulfate (Na2SO4), filtered and concentrated under reduced pressure to give diisopropyl succinate. | [References]
[1] Synthetic Communications, 2014, vol. 44, # 16, p. 2386 - 2392
[2] Phosphorus, Sulfur and Silicon and the Related Elements, 2004, vol. 179, # 6, p. 1187 - 1191
[3] Journal of Organic Chemistry, 1983, vol. 48, # 18, p. 3106 - 3108
[4] Journal of the Chemical Society, 1948, p. 631 |
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