| Identification | More | [Name]
N,N-Dimethylpropionamide | [CAS]
758-96-3 | [Synonyms]
DIMETHYLPROPIONAMIDE, N,N'-
N,N-DIMETHYLPROPIONAMIDE
PROPIONIC ACID N,N-DIMETHYLAMIDE
Dimethylamide of propionic acid
dimethylamideofpropionicacid
n,n-dimethyl-propanamid
N,N-Dimethylpropanamide
N,N-dimethyl-Propanamide
Propionamide, N,N-dimethyl-
propionamide,n,n-dimethyl
Propionic acid dimethylamide
N,N-Dimethylpropionamide98%
N,N-Dimethylpropionamide 98%
N,N-Dimethylpropionamide, 99+%
N,N-DIMETHYLPROPRIONAMIDE | [EINECS(EC#)]
212-064-9 | [Molecular Formula]
C5H11NO | [MDL Number]
MFCD00009301 | [Molecular Weight]
101.15 | [MOL File]
758-96-3.mol |
| Chemical Properties | Back Directory | [Appearance]
colourless liquid | [Melting point ]
-45 °C (lit.) | [Boiling point ]
174-175 °C (lit.) | [density ]
0.93
| [refractive index ]
1.438-1.442
| [Fp ]
63 °C
| [storage temp. ]
Store below +30°C. | [form ]
Liquid | [pka]
-0.41±0.70(Predicted) | [color ]
Colorless | [Specific Gravity]
0.920 | [Stability:]
Flammable. Incompatible with strong oxidizing agents. | [Water Solubility ]
SOLUBLE | [Dielectric constant]
33.1（Ambient） | [InChIKey]
MBHINSULENHCMF-UHFFFAOYSA-N | [CAS DataBase Reference]
758-96-3(CAS DataBase Reference) | [NIST Chemistry Reference]
Propanamide, N,N-dimethyl-(758-96-3) | [EPA Substance Registry System]
758-96-3(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed. | [Safety Statements ]
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
2 | [RTECS ]
UE3810000 | [TSCA ]
Yes | [HS Code ]
29241900 |
| Hazard Information | Back Directory | [Chemical Properties]
colourless liquid | [Uses]
N,N-Dimethylpropionamide has been used in the preparation of AST-type zeolite with a plate morphology. N,N-Dimethylpropionamide is strong donor solvent and coordinate to metal ions through the carbonyl oxygen atom. | [General Description]
Solvation structure of the zinc (II) ion in N,N-dimethylpropionamide was studied by Raman spectroscopy. N,N-Dimethylpropionamide is strong donor solvent and coordinate to metal ions through the carbonyl oxygen atom. | [Synthesis]
GENERAL METHOD: Carboxylic acid (0.3 mmol), catalyst (5 mol%), Xantphos (10 mol%), K2S2O8 (2 equiv.) and N,N-dimethylformamide (2 mL) were added to a 20 mL reaction tube. After sealing the reaction tube, the mixture was stirred at 160 °C for 12 h or until the reaction was complete. After completion of the reaction, the mixture was filtered and the filtrate was concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography with hexane-ethyl acetate (1:1, v/v) as eluent. | [Purification Methods]
Shake the amide over BaO for 1-2 days, then distil it under reduced pressure. [Beilstein 4 III 126.] | [References]
[1] Tetrahedron, 2016, vol. 72, # 50, p. 8210 - 8214 |
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