| Identification | More | [Name]
1,3-Dihydroxyadamantane | [CAS]
5001-18-3 | [Synonyms]
1,3-ADAMANTANDIOL
1,3-ADAMANTANEDIOL
1,3-DIHYDROXYADAMANTANE
ADAMANTANE-1,3-DIOL
AKOS BC-0470
TRICYCLO[3.3.1.13,7]DECANE-1,3-DIOL
Adamantanediol
1,3-Admantane-dimethanol
1,3-ADMANTANE
1,3-ADAMANTANEDIOL 98+%
1,3-Adamantanediol ,98.50%
1,3-Adamantanediol ,98.5%
1,3-Adamantadiol | [EINECS(EC#)]
218-362-5 | [Molecular Formula]
C10H16O2 | [MDL Number]
MFCD00154013 | [Molecular Weight]
168.23 | [MOL File]
5001-18-3.mol |
| Chemical Properties | Back Directory | [Appearance]
white crystal | [Melting point ]
~260 °C
| [Boiling point ]
320.4±10.0 °C(Predicted) | [density ]
1.368±0.06 g/cm3(Predicted) | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Solid | [pka]
14?+-.0.40(Predicted) | [color ]
White to Off-White | [Detection Methods]
HPLC,NMR,MS | [BRN ]
7013501 | [InChI]
InChI=1S/C10H16O2/c11-9-2-7-1-8(4-9)5-10(12,3-7)6-9/h7-8,11-12H,1-6H2 | [InChIKey]
MOLCWHCSXCKHAP-UHFFFAOYSA-N | [SMILES]
C12(O)CC3CC(CC(O)(C3)C1)C2 | [CAS DataBase Reference]
5001-18-3(CAS DataBase Reference) |
| Hazard Information | Back Directory | [Chemical Properties]
white crystal | [Uses]
1,3-Adamantanediol is used in the synthesis of novel dimethacrylate as possible dental monomers for dental resin mixtures.
| [Synthesis]
The procedure of Example 1 was repeated with the following adjustments: the catalyst was replaced with a vanadium (18 μmol) loaded V/Mont catalyst on montmorillonite; the dosage of adamantane was adjusted to 3 mM; tert-butyl acetate was chosen as the solvent; and the reaction conditions were set to continue at 100 °C for 96 h. The V/Mont catalysts were prepared according to the method described in Japanese Patent Application Publication (kokai) No. 2004-2234. ) No. 2004-2234. The specific operation includes: adding aqueous vanadium(III) chloride solution to montmorillonite (trade name: Kunipia F, produced by Kunimine Industries Co., Ltd.), followed by ion exchange, filtration, washing, drying and roasting at 800°C in air, to finally produce the desired catalysts. | [References]
[1] Journal of the American Chemical Society, 1989, vol. 111, # 17, p. 6749 - 6757
[2] Journal of the American Chemical Society, 2005, vol. 127, # 44, p. 15391 - 15393
[3] Tetrahedron Letters, 1999, vol. 40, # 11, p. 2165 - 2168
[4] Tetrahedron Letters, 1999, vol. 40, # 11, p. 2165 - 2168
[5] Patent: US2006/235245, 2006, A1. Location in patent: Page/Page column 6-7 |
|
|