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ChemicalBook--->CAS DataBase List--->36239-09-5

36239-09-5

36239-09-5 Structure

36239-09-5 Structure
IdentificationMore
[Name]

Ethyl malonyl chloride
[CAS]

36239-09-5
[Synonyms]

AURORA KA-3051
(CHLOROFORMYL)ACETIC ACID ETHYL ESTER
ETHYL 2-(CHLOROCARBONYL)ACETATE
ETHYL 3-CHLORO-3-OXOPROPIONATE
ETHYL (CHLOROFORMYL)ACETATE
ETHYL MALONYL CHLORIDE
MALONIC ACID MONOETHYL ESTER CHLORIDE
3-chloro-3-oxo-propanoicaciethylester
Propanoic acid, 3-chloro-3-oxo-, ethyl ester
Ethyl 3-chloro-3-oxopropionate, Ethyl (chloroformyl)acetate
ETHYL 3-CHLORO-3-OXOPROPIONATE,TECH
Ethyl Maloriyl Chloride
Ethyl malonyl chloride, pract., 90+%
Ethylmalonylchloride,95%
Ethyl malonyl chloride, tech., 90%
ETHYLMALONYLCHLORIDE,TECHNICAL
Ethyl (chloroformyl)acetate, Ethyl 3-chloro-3-oxopropionate
2-(Ethoxycarbonyl)acetyl chloride
Acetic acid, (chloroformyl)-, ethyl ester
Carbethoxyethanoyl chloride
[EINECS(EC#)]

252-934-5
[Molecular Formula]

C5H6Cl2O2
[MDL Number]

MFCD00000736
[Molecular Weight]

169.01
[MOL File]

36239-09-5.mol
Chemical PropertiesBack Directory
[Appearance]

clear yellow to brown liquid
[Boiling point ]

79-80 °C25 mm Hg(lit.)
[density ]

1.196 g/mL at 20 °C
[refractive index ]

n20/D 1.429(lit.)
[Fp ]

154 °F
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Soluble), DMSO (Sparingly), Ethyl Acetate (Slightly)
[form ]

Liquid
[pka]

9.35±0.46(Predicted)
[color ]

Clear yellow to brown
[Specific Gravity]

1.176
[Water Solubility ]

REACTS
[Sensitive ]

Moisture Sensitive
[BRN ]

636215
[Stability:]

Hygroscopic, Moisture Sensitive
[CAS DataBase Reference]

36239-09-5(CAS DataBase Reference)
[NIST Chemistry Reference]

Ethyl malonyl chloride(36239-09-5)
[Storage Precautions]

Moisture sensitive;Store under inert gas
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R14:Reacts violently with water.
R34:Causes burns.
[Safety Statements ]

S7:Keep container tightly closed .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/39:Wear suitable protective clothing and eye/face protection .
[RIDADR ]

UN 3265 8/PG 3
[WGK Germany ]

3
[F ]

10-21
[Hazard Note ]

Corrosive
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29171900
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

7-FLUORO-3,4-DIHYDRO-6-NITRO-3-OXOQUINOXALINE-2-CARBOXYLIC ACID-->2,3,4,5-Tetrahydro-5-methyl-1H-pyrido[4,3-b]indol-1-one-->5,6-DIHYDRO-4-(2-METHYL-2-PHENYLHYDRAZINO)-2-1H-PYRIDINONE-->2,4-Piperadinedione-->TERT-BUTYL ETHYL MALONATE-->4-Pyridazinecarboxylic acid, 2,3-dihydro-5-hydroxy-2-(3-methylbutyl)-3-oxo-6-(2-thienyl)-, ethyl ester-->ethyl 3-[(5-chloro-2-nitrophenyl)phenylamino]-3-oxopropionate
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Ethyl (chloroformyl)acetate(36239-09-5).msds
Hazard InformationBack Directory
[Chemical Properties]

clear yellow to brown liquid
[Uses]

Employed in the synthesis of 3-pyrrolin-2-ones via amidation with propargylamines and subsequent base catalyzed 5-exo-dig cyclization.1
[Uses]

Ethyl malonyl chloride is used in the syntheses of methanofullerodendimers and 3-pyrrolin-2-ones. It plays a vital role in the preparation of 3,5-disubstituted 1,2,4-oxadiazole derivatives, which are potential peptidomimetic building blocks. It is a versatile acylating agent for propargyl alcohols, hydrazines and amines.
[General Description]

Ethyl malonyl chloride is a versatile acylating agent for propargyl alcohols, hydrazines and amines.
Spectrum DetailBack Directory
[Spectrum Detail]

Ethyl malonyl chloride(36239-09-5)1HNMR
Ethyl malonyl chloride(36239-09-5)IR
Ethyl malonyl chloride(36239-09-5)FT-IR
Ethyl malonyl chloride(36239-09-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Ethyl malonyl chloride, tech., 90%(36239-09-5)
[Alfa Aesar]

Ethyl malonyl chloride, 95%(36239-09-5)
[Sigma Aldrich]

36239-09-5(sigmaaldrich)
[TCI AMERICA]

Ethyl Malonyl Chloride,>97.0%(GC)(T)(36239-09-5)
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