| Identification | More | [Name]
3'-Aminobenzanilide | [CAS]
16091-26-2 | [Synonyms]
3'-AMINOBENZANILIDE
3-AMINOBENZANILIDE
3-(AMINOPHENYL)BENZAMIDE
AKOS BB-8146
ART-CHEM-BB B025192
ASISCHEM B52474
M-BENZOYLAMINO ANILINE
N-(3-AMINOPHENYL)BENZAMIDE
3-Amino-N-phenylbenzamide
n-(3-aminophenyl)-benzamid
metaAmino Benzanilide
3-Benzoylaminoaniline | [EINECS(EC#)]
240-254-1 | [Molecular Formula]
C13H12N2O | [MDL Number]
MFCD00071750 | [Molecular Weight]
212.25 | [MOL File]
16091-26-2.mol |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [HazardClass ]
IRRITANT |
| Hazard Information | Back Directory | [Synthesis]
The general procedure for the synthesis of m-aminobenzanilide from N-(3-nitrophenyl)benzamide was as follows: N-(3-nitrophenyl)benzamide (10a) was dissolved in ethanol (20 mL) and an aqueous solution of iron powder (2.5 g) and ammonium chloride (0.53 g, 10 mmol) was added. The reaction mixture was heated to reflux for 2 hours. After completion of the reaction, it was filtered while hot, the filtrate was collected and rotary evaporated to dryness. The resulting solid was dissolved in acetone, filtered to remove insoluble matter, the filtrate was collected and rotary evaporated to dryness to give m-aminobenzanilide (11a) in 89.8% yield. | [References]
[1] Synthesis (Germany), 2012, vol. 44, # 16, p. 2579 - 2586
[2] Synthetic Communications, 2000, vol. 30, # 20, p. 3639 - 3644
[3] Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2000, vol. 39, # 9, p. 709 - 711
[4] Patent: CN106699755, 2017, A. Location in patent: Paragraph 0103; 0195; 0196
[5] Journal of Chemical Research, 2006, # 4, p. 223 - 224 |
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