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ChemicalBook--->CAS DataBase List--->14602-86-9

14602-86-9

14602-86-9 Structure

14602-86-9 Structure
IdentificationMore
[Name]

(-)-MENTHYL CHLOROFORMATE
[CAS]

14602-86-9
[Synonyms]

(1R,2S,5R)-(-)-MENTHYLCHLOROFORMATE
(-)-(1R)-MENTHYL CHLOROFORMATE
(1R)-(-)-MENTHYL CHLOROFORMATE
(-)-CHLOROFORMYLOXY-P-MENTHANE
MCF
(-)-MENTHYL CHLOROFORMATE
Chloroformic acid (1R)-menthyl ester~L-Menthyl chloroformate
L-p-menth-3-yl chloroformate
(-)-(1R)-Menthyl chloroformate (99% EE/GLC)
(1R)-(-)-MENTHYL CHLOROFORMATE 95+%
L-MenthylChloroformate
(1R)-Menthylester
Chloroformicacid
Carbonochloridic acid, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester
chloroformic acid (1r)-menthyl ester
(-)-Menthyloxycarbonyl chloride
(S)-Menthyl chloroformate
Chloroformic acid (1R,3R,4S)-p-menthane-3-yl ester
Chloroformic acid [[1R,2S,5R,(-)]-2-isopropyl-5-methylcyclohexyl] ester
(-)-Chloroformic acid 2-(1-methylethyl)-5-methylcyclohexyl ester
[EINECS(EC#)]

672-624-7
[Molecular Formula]

C11H19ClO2
[MDL Number]

MFCD00009694
[Molecular Weight]

218.72
[MOL File]

14602-86-9.mol
Chemical PropertiesBack Directory
[Boiling point ]

108-109 °C11 mm Hg(lit.)
[density ]

1.031 g/mL at 20 °C(lit.)
[vapor pressure ]

0.01 psi ( 20 °C)
[refractive index ]

n20/D 1.459
[Fp ]

158 °F
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Sparingly), Methanol (Sparingly)
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[Optical Rotation]

[α]20/D 83°, c = 1 in chloroform
[Sensitive ]

Moisture Sensitive
[BRN ]

2414686
[CAS DataBase Reference]

14602-86-9(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

T,N
[Risk Statements ]

R23:Toxic by inhalation.
R34:Causes burns.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 3277 6.1/PG 2
[WGK Germany ]

3
[F ]

10-19-21
[HS Code ]

2915.90.5010
[HazardClass ]

6.1
[PackingGroup ]

II
Raw materials And Preparation ProductsBack Directory
[Raw materials]

L-Menthol
[Preparation Products]

Isobutyric acid-->Thioglycolic acid-->Ethyl 5-[3-(4,6-dimethoxy pyrimidyl-2-yl)ureido]methylpyrazolyl-4-carboxylic ester-->FENOTHIOCARB-->2-Naphthalenethiol-->Benzyl formate-->Alclometasone Dipropionate-->TIADINIL-->BENFURACARB-->biodegrddable finishing agent for fabric-->Butyl formate-->1,2-Pentanediol-->Geranyl formate-->azafenidin-->OCTYL FORMATE-->cis-3-Hexenyl formate
Hazard InformationBack Directory
[Uses]

Readily forms a chloroimidodicarbonate which asymmetrically chlorinates silyl enol ethers under mild conditions and in good yields.
Spectrum DetailBack Directory
[Spectrum Detail]

(-)-MENTHYL CHLOROFORMATE(14602-86-9)1HNMR
(-)-MENTHYL CHLOROFORMATE(14602-86-9)FT-IR
(-)-MENTHYL CHLOROFORMATE(14602-86-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

(1R)-(-)-Menthyl chloroformate, 95%(14602-86-9)
[Sigma Aldrich]

14602-86-9(sigmaaldrich)
[TCI AMERICA]

(-)-Menthyl Chloroformate,>97.0%(T)(14602-86-9)
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