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ChemicalBook CAS DataBase List Boron triiodide
13517-10-7

Boron triiodide synthesis

4synthesis methods
Boron triiodide can be synthesized by refluxing lithium borohydride and iodine in hexane, or by reacting alkali metal borohydride with iodine at a suitable temperature.
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Yield:13517-10-7 45-50

Reaction Conditions:

byproducts: HI, I2; at 200°C, under N2; removing of I2: reaction mixt. dissolved in CS2, addn. of Zn or Hg, filtering, evapn. of solvent, sublimation in vac. twice;

References:

Schumb, W. C.;Gamble, E. L.;Danus, M. B. [Journal of the American Chemical Society,1949,vol. 71,p. 3225 - 3229] [Gmelin Handbuch der Anorganischen Chemie,Gmelin Handbook: B: SVol.1, 4.6, page 204 - 209]

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