2H-Thiopyran-4-carboxaldehyde, tetrahydro-, 1,1-dioxide synthesis
- Product Name:2H-Thiopyran-4-carboxaldehyde, tetrahydro-, 1,1-dioxide
- CAS Number:494210-61-6
- Molecular formula:C6H10O3S
- Molecular Weight:162.21
64096-87-3
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$24.73/250mgs:
494210-61-6
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$285.00/100mg
Yield: 73%
Reaction Conditions:
Stage #1:1,1-dioxo-hexahydro-1λ6-thiopyran-4-carboxylic acid with 2,6-dimethylpyridine;nickel(II) bromide trihydrate;4,4'-di-tert-butyl-2,2'-bipyridine;zinc;dimethyl dicarbonate in ethyl acetate for 0.25 h;Inert atmosphere;Green chemistry;
Stage #2: with diphenylsilane in ethyl acetate at 60; for 16 h;Inert atmosphere;Green chemistry;
References:
Iosub, Andrei V.;Morav?ík, ?tefan;Wallentin, Carl-Johan;Bergman, Joakim [Organic Letters,2019,vol. 21,# 19,p. 7804 - 7808] Location in patent:supporting information
50675-19-9
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$45.00/50mg
494210-61-6
34 suppliers
$285.00/100mg
473254-28-3
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$45.00/10mg
494210-61-6
34 suppliers
$285.00/100mg