2-Methyl-1,3-dioxolane-2-propanoic Acid synthesis
- Product Name:2-Methyl-1,3-dioxolane-2-propanoic Acid
- CAS Number:4388-57-2
- Molecular formula:C7H12O4
- Molecular Weight:160.17
107-21-1
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123-76-2
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4388-57-2
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$245.00/500mg
Yield:4388-57-2 86%
Reaction Conditions:
with 1.3 wt% Na-β zeolite (Na/Al ratio: 0.5; Si/Al ratio: 25) in cyclohexane at 120; for 1 h;Dean-Stark;
Steps:
2.4. Preparation of ketals from ethyl levulinate with polyols
General procedure: In a typical reaction, a mixture of ethyl levulinate (1 g, 6.94 mmol),polyol (1-2 mole ratio w.r.t carbonyl compounds), 10 wt% of -zeolitecatalyst w.r.t. EL (100 mg), and cyclohexane (5 mL) were taken in a 20mL reaction tube. The reaction was carried out in METLER TOLEDOEasy Max 102 glass reactor with the help of Dean-Stark setup at 120 C(for ethylene glycol) or 140 C (for glycerol) at 1000 rpm for 1 h (forethylene glycol) or 4 h (for glycerol). After the reaction, the solid catalystwas separated from product mixture by centrifugation and the supernatantliquid was rotatory evaporated to remove the cyclohexanesolvent. The obtained liquid products were characterized by 13C NMR.Conversion of reactants and yield of products were analysed by Varian450 gas chromatograph (GC) with a flame ionization detector (FID). Theconditions for gas chromatography were as follows: ZB-5MS column, 30m × 0.25 mm × 0.25 m; carrier gas: nitrogen; injection temperature,250 C; detector temperature, 350 C; oven temperature, 80 C to 220 Cat a programmed heating rate of 20 C/min and 5 min hold at 220 C.
References:
Gundekari, Sreedhar;Mani, Mariappan;Mitra, Joyee;Srinivasan, Kannan [Molecular catalysis,2022,vol. 524,art. no. 112269]
941-43-5
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4388-57-2
11 suppliers
$245.00/500mg
107-21-1
1370 suppliers
$10.00/25g
123-76-2
492 suppliers
$5.00/25g
4388-57-2
11 suppliers
$245.00/500mg
62603-41-2
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143674-66-2
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4388-57-2
11 suppliers
$245.00/500mg
35351-33-8
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4388-57-2
11 suppliers
$245.00/500mg