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ChemicalBook >> CAS DataBase List >> (R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate

(R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate

(R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate price.
  • $67 - $2476
  • Product name: (R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate
  • CAS: 791616-63-2
  • MF: C50H57O4P
  • MW: 752.98
  • EINECS:
  • MDL Number:MFCD10567009
  • Synonyms:(R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-binaphthyl-2,2μ-diyl hydrogenphosphate;(R)-TRIP, (11bR)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (R)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate;(R)-3,3'-Bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate >=97.5% (HPLC);(S)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-binaphthyl-2,2μ-diyl hydrogenphosphate;(2r)-4-hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(R)-3,3'-Bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'- diyl Hydrogen Phosphate,99%e.e.;(11BR)-4-HYDROXY-2,6-BIS[2,4,6-TRIS(1-METHYLETHYL)PHENYL]-4-OXIDE-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN,98%,(99%EE);(R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate
19 prices
Selected condition：
Brand
  • AK Scientific
  • Ambeed
  • American Custom Chemicals Corporation
  • ChemScene
  • ChemSupplyAustralia
  • Crysdot
  • Matrix Scientific
  • Sigma-Aldrich
  • Strem Chemicals
  • SynQuest Laboratories
Package
  • 5MG
  • 100mg
  • 250mg
  • 500mg
  • 1g
  • 5g
  • ManufacturerAK Scientific
  • Product numberCS-0030546
  • Product description(R)-TRIP
  • Packaging1g
  • Price$1800
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA623140
  • Product description(11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee
  • Packaging100mg
  • Price$71
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA623140
  • Product description(11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee
  • Packaging250mg
  • Price$132
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA623140
  • Product description(11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee
  • Packaging1g
  • Price$430
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA623140
  • Product description(11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee
  • Packaging5g
  • Price$1302
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCCH0040720
  • Product description(11-BETA-R)-4-HYDROXY-2,6-BIS-[2,4,6-TRIS-(1-METHYLETHYL)PHENYL]DINAPHTHO[2,1-D,1',2'-F]-1,3,2-DIOXAPHOSPHEPIN-4-OXIDE 95.00%
  • Packaging5MG
  • Price$496.52
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-0030546
  • Product description(R)-TRIP 99.25%
  • Packaging100mg
  • Price$67
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-0030546
  • Product description(R)-TRIP 99.25%
  • Packaging250mg
  • Price$128
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-0030546
  • Product description(R)-TRIP 99.25%
  • Packaging1g
  • Price$428
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-0030546
  • Product description(R)-TRIP 99.25%
  • Packaging5g
  • Price$1280
  • Updated2021-12-16
  • Buy
  • ManufacturerChemSupplyAustralia
  • Product number300919
  • Product description(R)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate, 97%
  • Packaging100mg
  • Price$231
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD12030667
  • Product description(R)-TRIP 95+%
  • Packaging1g
  • Price$2322
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number118703
  • Product description(R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.8%
  • Packaging250mg
  • Price$750
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number118703
  • Product description(R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.8%
  • Packaging500mg
  • Price$1350
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number118703
  • Product description(R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.8%
  • Packaging1g
  • Price$2476
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number689890
  • Product description(R)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate ≥97.5% (HPLC)
  • Packaging100mg
  • Price$302
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific CS-0030546 (R)-TRIP 1g $1800 2021-12-16 Buy
Ambeed A623140 (11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee 100mg $71 2021-12-16 Buy
Ambeed A623140 (11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee 250mg $132 2021-12-16 Buy
Ambeed A623140 (11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee 1g $430 2021-12-16 Buy
Ambeed A623140 (11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%99%ee 5g $1302 2021-12-16 Buy
American Custom Chemicals Corporation CCH0040720 (11-BETA-R)-4-HYDROXY-2,6-BIS-[2,4,6-TRIS-(1-METHYLETHYL)PHENYL]DINAPHTHO[2,1-D,1',2'-F]-1,3,2-DIOXAPHOSPHEPIN-4-OXIDE 95.00% 5MG $496.52 2021-12-16 Buy
ChemScene CS-0030546 (R)-TRIP 99.25% 100mg $67 2021-12-16 Buy
ChemScene CS-0030546 (R)-TRIP 99.25% 250mg $128 2021-12-16 Buy
ChemScene CS-0030546 (R)-TRIP 99.25% 1g $428 2021-12-16 Buy
ChemScene CS-0030546 (R)-TRIP 99.25% 5g $1280 2021-12-16 Buy
ChemSupplyAustralia 300919 (R)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate, 97% 100mg $231 2021-12-16 Buy
Crysdot CD12030667 (R)-TRIP 95+% 1g $2322 2021-12-16 Buy
Matrix Scientific 118703 (R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.8% 250mg $750 2021-12-16 Buy
Matrix Scientific 118703 (R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.8% 500mg $1350 2021-12-16 Buy
Matrix Scientific 118703 (R)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate 99.8% 1g $2476 2021-12-16 Buy
Sigma-Aldrich 689890 (R)-3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate ≥97.5% (HPLC) 100mg $302 2024-03-01 Buy

Properties

Boiling point :814.2±75.0 °C(Predicted)
Density :1.17±0.1 g/cm3(Predicted)
storage temp. :Inert atmosphere,Room Temperature
pka :1.12±0.20(Predicted)
form :Powder
color :white to light-yellow
InChIKey :AGQAQYPGJDBIQR-UHFFFAOYSA-N
SMILES :O=P1(OC2C(C3C(=CC(C(C)C)=CC=3C(C)C)C(C)C)=CC3=CC=CC=C3C=2C2C3=CC=CC=C3C=C(C3C(=CC(C(C)C)=CC=3C(C)C)C(C)C)C=2O1)O

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

Versatile organocatalyst. Uses include asymmetric reductive amination, enantioselective Diels-Alder reactions and asymmetric counteranion-directed catalysis (ACDC). Can be used in cooperation with chiral iridium complexes to catalyze greener asymmetric reductive amination using hydrogen gas.

Metal-Br?nsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

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