Methyl 2-(bromomethyl)acrylate

Modify Date: 2024-01-08 13:47:56

Methyl 2-(bromomethyl)acrylate structure	Common Name	Methyl 2-(bromomethyl)acrylate
	CAS Number	4224-69-5	Molecular Weight	179.012
	Density	1.5±0.1 g/cm3	Boiling Point	187.1±0.0 °C at 760 mmHg
	Molecular Formula	C5H7BrO2	Melting Point	N/A
	MSDS	ChineseUSA	Flash Point	78.3±0.0 °C
	Symbol	GHS05, GHS07	Signal Word	Danger

Purity		Quantity		Budget		Inquiry

• Properties

• Articles4

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 Contents:

• Names

• Chemical & Physical Properties

• MSDS

• Toxicological Info

• Safety Info

• Synthetic Route

• Customs

• Articles

• Synonyms

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 Names

Name	Methyl 2-(bromomethyl)acrylate
Synonym	More Synonyms

 Chemical & Physical Properties

Density	1.5±0.1 g/cm3
Boiling Point	187.1±0.0 °C at 760 mmHg
Molecular Formula	C5H7BrO2
Molecular Weight	179.012
Flash Point	78.3±0.0 °C
Exact Mass	177.962936
PSA	26.30000
LogP	1.88
Vapour Pressure	0.6±0.3 mmHg at 25°C
Index of Refraction	1.471
Storage condition	2-8°C

 MSDS

Methyl 2-(bromomethyl)acrylate MSDS(Chinese)

 Toxicological Information

CHEMICAL IDENTIFICATION RTECS NUMBER : AS4900000 CHEMICAL NAME : Acrylic acid, 2-(bromomethyl)-, methyl ester CAS REGISTRY NUMBER : 4224-69-5 LAST UPDATED : 199710 DATA ITEMS CITED : 2 MOLECULAR FORMULA : C5-H7-Br-O2 MOLECULAR WEIGHT : 179.03 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : Standard Draize test ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit REFERENCE : EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-1090-1048S

 Safety Information

Symbol	GHS05, GHS07
Signal Word	Danger
Hazard Statements	H315-H318-H335
Precautionary Statements	P261-P280-P305 + P351 + P338
Personal Protective Equipment	Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes	Xi:Irritant;
Risk Phrases	R36/37/38
Safety Phrases	S26-S36-S37/39
RIDADR	UN 2810 6.1/PG 2
WGK Germany	3
RTECS	AS4900000
HS Code	2916190090

 Synthetic Route

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Methyl 2-(hydro... CAS#:15484-46-5 ~86% Methyl 2-(bromo... CAS#:4224-69-5

Literature: Luehr, Susan; Holz, Jens; Zayas, Odalys; Seidelmann, Oliver; Domke, Lutz; Boerner, Armin Tetrahedron Asymmetry, 2013 , vol. 24, # 7 p. 395 - 401

dms CAS#:75-18-3 Methyl 2-(hydro... CAS#:15484-46-5 ~89% Methyl 2-(bromo... CAS#:4224-69-5

Literature: Barrera, Jaime Bermejo; Silva, Margarita Hernandez; De Mon, Melchor Alvarez; Ranieri, Juan Pablo Pivel Patent: US2003/199575 A1, 2003 ;

Methyl 3-bromo-... CAS#:22262-60-8 ~94% Methyl 2-(bromo... CAS#:4224-69-5

Literature: Charlton, J. L.; Sayeed, V. A.; Lypka, G. N. Synthetic Communications, 1981 , vol. 11, # 11 p. 931 - 934

 Customs

HS Code	2916190090
Summary	2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Structure-activity relationships of tulipalines, tuliposides, and related compounds as inhibitors of MurA. Bioorg. Med. Chem. Lett. 20 , 5757-62, (2010) The enzyme MurA performs an essential step in peptidoglycan biosynthesis and is therefore a target for the discovery of novel antibacterial compounds. We report here the inhibition of MurA by natural ...	Detail
Diastereocontrolled synthesis of enantioenriched 3,4-disubstituted beta-prolines. J. Org. Chem. 72 , 398, (2007) Enantioenriched 3,4-disubstituted beta-prolines have been prepared with a high diastereocontrol through a carbometalation reaction or through a domino Michael addition/carbometalation reaction.	Detail
Use of methyl 2-(bromomethyl) acrylate as a chain-transfer agent to yield functionalized macromonomers via conventional and living radical polymerizations. Bon, SAF, et al. Macromolecules 33(16) , 5819-5824, (2000)

 Articles4

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