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(R)-VAPOL

(R)-VAPOL Suppliers list
Company Name: Aladdin Scientific
Tel:
Email: tp@aladdinsci.com
Products Intro: Product Name:(3R)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol
CAS:147702-16-7
Purity:98%,99%ee Package:$62.9/25mg;$192.9/100mg;$760.9/500mg;Bulk package Remarks:98%,99%ee
Company Name: Shanghai Likang New Materials Co., Limited
Tel: +86-16631818819 +86-17736933208
Email: 3684455296@qq.com
Products Intro: Product Name:(3R)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol
CAS:147702-16-7
Purity:99% Package:100KG;10KG;5KG;1KG
Company Name: ABCR GmbH & CO. KG
Tel: 49 721 95061 0
Email: info@abcr.de
Products Intro:
Company Name: J & K SCIENTIFIC LTD.  
Tel: 18210857532
Email: jkinfo@jkchemical.com
Products Intro: Product Name:(3R)-(-)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct, min. 98% (R)-VAPOL
CAS:147702-16-7
Purity:min. 98% Package:100mg;500mg
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Tel: 021-61259108 18621169109
Email: market03@meryer.com
Products Intro: Product Name:(3R)-(-)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloroMethane adduct
CAS:147702-16-7
Purity:98% (R)-VAPOL Remarks:AAM176623
(R)-VAPOL Basic information
Reaction
Product Name:(R)-VAPOL
Synonyms:(R)-VAPOL 97%;(R)-VAPOL,99%e.e.;(S)-2,2'-DIPHENYL-(4-BIPHENANTHROL);(R)-VAPOL;(S)-VAPOL;(R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL);(3R)-(-)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT;(3S)-(+)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT
CAS:147702-16-7
MF:C40H26O2
MW:538.63
EINECS:
Product Categories:BINOL Series;Chiral Oxygen
Mol File:147702-16-7.mol
(R)-VAPOL Structure
(R)-VAPOL Chemical Properties
Melting point 225-229 °C
Boiling point 712.2±60.0 °C(Predicted)
alpha -123.4° (c 1.0, THF)
density 1.286±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka8.37±0.30(Predicted)
form Powder
color white to pale yellow
optical activity[α]20/D -144°, c = 1 in chloroform
Safety Information
Hazard Codes Xn
Risk Statements 37/38-40-41
Safety Statements 26-36/37/39
WGK Germany 3
MSDS Information
(R)-VAPOL Usage And Synthesis
Reaction
  1. Chiral ligand used in catalytic asymmetric aziridination.
  2. Chiral ligand used in catalytic asymmetric imino aldol reaction.
  3. Chiral ligand used in catalytic asymmetric Petasis reaction. 
Reactions of 147702-16-7
UsesVAPOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.
(R)-VAPOL Preparation Products And Raw materials
Tag:(R)-VAPOL(147702-16-7) Related Product Information
R-3,3'-bis[4-(trifluoroMethyl)phenyl]-[1,1'-Binaphthalene]-2,2'-diol Dichloromethane (R)-VAPOL HYDROGENPHOSPHATE (S)-VAPOL hydrogenphosphate (R)-VAPOL

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