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4-Bromobiphenyl

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4-Bromobiphenyl Basic information
Product Name:4-Bromobiphenyl
Synonyms:(4-bromophenyl)benzene;1,1’-(biphenyl,-bromo-;1,1’-Biphenyl,4-bromo-;1,1’-biphenyl,-bromo-(4-bromobiphenyl);1’-Biphenyl,4-bromo-1;4-Biphenyl bromide;4-biphenylylbromide;4-Brom-biphenyl
CAS:92-66-0
MF:C12H9Br
MW:233.1
EINECS:202-176-6
Product Categories:blocks;Bromides;Liquid Crystal intermediates;Biphenyl derivatives;Aromatic Compounds;Biphenyl & Diphenyl ether;Yellow crystalline powder;A-BAnalytical Standards;Alpha Sort;AromaticsAlphabetic;B;BI - BZChemical Class;Bromo;Chemical Class;Halogenated;Volatiles/ Semivolatiles;Aryl;C9 to C12;Halogenated Hydrocarbons;bc0001;92-66-0
Mol File:92-66-0.mol
4-Bromobiphenyl Structure
4-Bromobiphenyl Chemical Properties
Melting point 82-86 °C(lit.)
Boiling point 310 °C(lit.)
density 0.9327
refractive index 1.6565 (estimate)
Fp 143 °C
storage temp. Sealed in dry,Room Temperature
solubility dioxane: soluble1g/10 mL, clear, colorless to very faintly yellow
form Crystalline Flakes
color Almost white to slightly yellow
Water Solubility Insoluble
BRN 1907453
Stability:Stable. Incompatible with oxidizing agents.
InChIKeyPKJBWOWQJHHAHG-UHFFFAOYSA-N
CAS DataBase Reference92-66-0(CAS DataBase Reference)
NIST Chemistry Reference
EPA Substance Registry System4-Bromobiphenyl (92-66-0)
Safety Information
Hazard Codes Xi,N,Xn
Risk Statements 36/37/38-50/53-41-37/38-22
Safety Statements 22-24/25-37/39-26-61-60-39
RIDADR UN 3152 9/PG 2
WGK Germany 3
RTECS DV1750100
TSCA T
HazardClass IRRITANT
PackingGroup 
HS Code 29036990
MSDS Information
ProviderLanguage
4-Bromobiphenyl English
SigmaAldrich English
ACROS English
ALFA English
4-Bromobiphenyl Usage And Synthesis
Chemical PropertiesWhite powder
Uses4-Bromobiphenyl is used as a reagent in the synthesis of spirooxindole derivatives for use as AMPK activators.  It is also used as a reagent in the preparation of indenoindole derivatives as organic electroluminescent device materials.
Uses4-Bromobiphenyl is used as halogenated hydrocarbon and Intermediates of Liquid Crystals. It is also used in used in the synthesis of 4-biphenylthiolate.
General DescriptionColorless crystals. Insoluble in water.
Air & Water ReactionsInsoluble in water.
Reactivity Profile4-Bromobiphenyl may be sensitive to light, and it can react with oxidizing materials.
Fire HazardCombustible.
SynthesisInto a 250 ml reactor equipped with magnetic agitation means, a condenser, a dropping funnel, and a thermometer, the following materials were introduced:
(i) 15.4 g biphenyl (0.1 M);
(ii) 100 ml solvent
at ambient temperature Then, over 10 min, the bromine was poured therein (39.2 g/0.22 M), whereupon the mixture was agitated for a varying period of time at ambient temperature. Upon completion of the reaction, the excess bromine was consumed by sodium or potassium sulfite or bisulfite. The organic phase was washed, dried and diluted to a given volume, and analyzed by CPG to give 4-Bromobiphenyl.
Purification MethodsCrystallise the biphenyl from abolute EtOH and dry it in vacuo.[Beilstein 5 IV 1819.]
Tag:4-Bromobiphenyl(92-66-0) Related Product Information
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