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ChemicalBook >> CAS DataBase List >> 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent

1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent

1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent price.
  • $28 - $914.38
  • Product name: 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent
  • CAS: 887144-97-0
  • MF: C10H10F3IO
  • MW: 330.09
  • EINECS:
  • MDL Number:MFCD10567056
  • Synonyms:1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent;1,3-dihydro-3,3-diMethyl-1-(trifluoroMethyl)-1,2-benziodoxole;1,3-Dhydro-3,3-diMethyl-1-(trifluoroMethyl)-1,2-benziodoxole;3,3-DMethyl-1-(trifluoroMethyl)-1,2-benziodoxole;1,3-Dihydro-3,3-diMethyl-1-(trifluoroMethyl)-1,2-b;3,3-DiMethyl-1-(trifluoroMethyl)-1,2-benziodoxole 95%;3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole / TOGNI A;3,3-DiMethyl-1-(trifluoroMethyl)-1,2-benziodoxole (Togni‘s reagent)
25 prices
Selected condition：
Brand
  • AK Scientific
  • Alichem
  • Apolloscientific
  • Biosynth Carbosynth
  • Chem-Impex
  • ChemSupplyAustralia
  • Medical Isotopes, Inc.
  • Sigma-Aldrich
  • SynQuest Laboratories
  • TCI Chemical
  • TRC
Package
  • 100mg
  • 250mg
  • 500mg
  • 1g
  • 2g
  • 5g
  • 10g
  • 25g
  • ManufacturerAK Scientific
  • Product numberB593
  • Product description3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole
  • Packaging1g
  • Price$358
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number887144970
  • Product description1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole
  • Packaging5g
  • Price$285.32
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number887144970
  • Product description1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole
  • Packaging10g
  • Price$459.64
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number887144970
  • Product description1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole
  • Packaging25g
  • Price$914.38
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberPC56207
  • Product description3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 98%
  • Packaging250mg
  • Price$28
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberPC56207
  • Product description3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 98%
  • Packaging1g
  • Price$48
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberPC56207
  • Product description3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 98%
  • Packaging5g
  • Price$168
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD39543
  • Product description3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole
  • Packaging2g
  • Price$300
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD39543
  • Product description3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole
  • Packaging1g
  • Price$200
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD39543
  • Product description3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole
  • Packaging500mg
  • Price$150
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD39543
  • Product description3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole
  • Packaging250mg
  • Price$100
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD39543
  • Product description3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole
  • Packaging100mg
  • Price$75
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number36165
  • Product description3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole,≥98%(NMR)Hazmat ≥98%(NMR)
  • Packaging100MG
  • Price$52
  • Updated2021-12-16
  • Buy
  • ManufacturerChemSupplyAustralia
  • Product number300939
  • Product description1-Trifluoromethyl-3,3-dimethyl-1,2-benziodoxole
  • Packaging1g
  • Price$93.5
  • Updated2021-12-16
  • Buy
  • ManufacturerMedical Isotopes, Inc.
  • Product number62162
  • Product descriptionTogni??sReagent
  • Packaging1g
  • Price$290
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number696641
  • Product description3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 95%
  • Packaging250mg
  • Price$71.4
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific B593 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 1g $358 2021-12-16 Buy
Alichem 887144970 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 5g $285.32 2021-12-16 Buy
Alichem 887144970 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 10g $459.64 2021-12-16 Buy
Alichem 887144970 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 25g $914.38 2021-12-16 Buy
Apolloscientific PC56207 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 98% 250mg $28 2021-12-16 Buy
Apolloscientific PC56207 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 98% 1g $48 2021-12-16 Buy
Apolloscientific PC56207 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 98% 5g $168 2021-12-16 Buy
Biosynth Carbosynth FD39543 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 2g $300 2021-12-16 Buy
Biosynth Carbosynth FD39543 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 1g $200 2021-12-16 Buy
Biosynth Carbosynth FD39543 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 500mg $150 2021-12-16 Buy
Biosynth Carbosynth FD39543 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 250mg $100 2021-12-16 Buy
Biosynth Carbosynth FD39543 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 100mg $75 2021-12-16 Buy
Chem-Impex 36165 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole,≥98%(NMR)Hazmat ≥98%(NMR) 100MG $52 2021-12-16 Buy
ChemSupplyAustralia 300939 1-Trifluoromethyl-3,3-dimethyl-1,2-benziodoxole 1g $93.5 2021-12-16 Buy
Medical Isotopes, Inc. 62162 Togni??sReagent 1g $290 2021-12-16 Buy
Sigma-Aldrich 696641 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole 95% 250mg $71.4 2024-03-01 Buy

Properties

Melting point :75-79 °C
storage temp. :2-8°C
solubility :Chloroform (Slightly), Methanol (Slightly)
form :powder
color :white to off-white
Stability :Moisture Sensitive
InChI :InChI=1S/C10H10F3IO/c1-9(2)7-5-3-4-6-8(7)14(15-9)10(11,12)13/h3-6H,1-2H3
InChIKey :HVAPLSNCVYXFDQ-UHFFFAOYSA-N
SMILES :I1(C(F)(F)F)C2=CC=CC=C2C(C)(C)O1

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H228 Flammable solid Flammable solids Category 1
Category 2		 Danger
Warning		 GHS hazard pictograms P210, P240,P241, P280, P370+P378
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Selective trifluoromethylation of 1,3-disubstituted arenes through iridium-catalyzed arene borylation and copper-catalyzed trifluoromethylationCopper-catalyzed trifluoromethylation of aryl- and alkenylboronic acids with electrophilic trifluoromethylating reagentPd-catalyzed electrophilic ortho-trifluoromethylation of arenes using trifluoroacetic acid as a promotorUsed in the Preparation ofTrifluoromethylimidoylethyl substituted heterocycles via bis(trifluoromethylsulfonyl)amine-catalyzed Rotter type reaction of heterocycles with nitriles in presence of trifluoromethylbenziodoxoleStereoselective synthesis of α-trifluoromethyl aldehydes via trimethylbenzylimidazolidinone and copper-catalyzed enantioselective α-trifluoromethylation of aldehydes with iodonium salts

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