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ChemicalBook >> CAS DataBase List >> Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)

Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) price.
  • $20.68 - $1064
  • Product name: Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
  • CAS: 373650-12-5
  • MF: C38H28O4P2.C4H6O4Ru
  • MW: 829.741
  • EINECS:
  • MDL Number:MFCD09753024
  • Synonyms:Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II);(S)-Ru(OAc)2(SEGPHOS(R));Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos];Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)];Diacetoxyruthenium, [4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl )-1,3-benzodioxol-5-yl]-diphenyl-phosphane;Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-be...;(S)-Ru(OAc)2(SEGPHOS);RU(OAC)2[(S)-SEGPHOS]
11 prices
Selected condition：
Brand
  • Ambeed
  • American Custom Chemicals Corporation
  • Chemenu
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 5MG
  • 50mg
  • 100mg
  • 250mg
  • 1g
  • 5g
  • ManufacturerAmbeed
  • Product numberA252714
  • Product descriptionDiacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) 98%
  • Packaging250mg
  • Price$85
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA252714
  • Product descriptionDiacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) 98%
  • Packaging1g
  • Price$238
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA252714
  • Product descriptionDiacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) 98%
  • Packaging5g
  • Price$780
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0013136
  • Product descriptionDIACETATO-[(S)-(-)-5,5'-BIS-(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM-(II) 95.00%
  • Packaging5MG
  • Price$496.19
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM102980
  • Product descriptionDiacetato[(S)-(-)-5,5''-bis(diphenylphosphino)-4,4''-bi-1,3-benzodioxole]ruthenium(II) 98%
  • Packaging1g
  • Price$379
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM102980
  • Product descriptionDiacetato[(S)-(-)-5,5''-bis(diphenylphosphino)-4,4''-bi-1,3-benzodioxole]ruthenium(II) 98%
  • Packaging5g
  • Price$1064
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number693243
  • Product description(S)-Ru(OAc)2(SEGPHOS?)
  • Packaging100mg
  • Price$20.68
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number693243
  • Product description(S)-Ru(OAc)2(SEGPHOS?)
  • Packaging50mg
  • Price$26.2
  • Updated2023-01-07
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0169
  • Product descriptionDiacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)]
  • Packaging250mg
  • Price$53
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0169
  • Product descriptionDiacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)]
  • Packaging1g
  • Price$158
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0169
  • Product descriptionDiacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)]
  • Packaging5g
  • Price$436
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Ambeed A252714 Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) 98% 250mg $85 2021-12-16 Buy
Ambeed A252714 Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) 98% 1g $238 2021-12-16 Buy
Ambeed A252714 Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) 98% 5g $780 2021-12-16 Buy
American Custom Chemicals Corporation ING0013136 DIACETATO-[(S)-(-)-5,5'-BIS-(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]RUTHENIUM-(II) 95.00% 5MG $496.19 2021-12-16 Buy
Chemenu CM102980 Diacetato[(S)-(-)-5,5''-bis(diphenylphosphino)-4,4''-bi-1,3-benzodioxole]ruthenium(II) 98% 1g $379 2021-12-16 Buy
Chemenu CM102980 Diacetato[(S)-(-)-5,5''-bis(diphenylphosphino)-4,4''-bi-1,3-benzodioxole]ruthenium(II) 98% 5g $1064 2021-12-16 Buy
Sigma-Aldrich 693243 (S)-Ru(OAc)2(SEGPHOS?) 100mg $20.68 2024-03-01 Buy
Sigma-Aldrich 693243 (S)-Ru(OAc)2(SEGPHOS?) 50mg $26.2 2023-01-07 Buy
Strem Chemicals 44-0169 Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)] 250mg $53 2024-03-01 Buy
Strem Chemicals 44-0169 Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)] 1g $158 2024-03-01 Buy
Strem Chemicals 44-0169 Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)] 5g $436 2024-03-01 Buy

Properties

Melting point :>100°C
storage temp. :2-8°C
form :solid
color :yellow to black
Sensitive :air sensitive
InChIKey :BHGLLIGZFQVMBJ-UHFFFAOYSA-L
SMILES :C1(P(C2=CC=CC=C2)C2C=CC=CC=2)C=CC2OCOC=2C=1C1=C(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC2OCOC1=2.O(C(=O)C)[Ru]OC(=O)C

Safety Information

Symbol(GHS):
Signal word:
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
Precautionary statements:

Description

(S)-Ru(OAc)2(SEGPHOS?) can be used as a catalyst:
  • To prepare highly chemo, enantio, and diastereoselective primary β-amino lactams by asymmetric reductive amination of racemic β-keto lactams.
  • To synthesize chiral primary diarylmethylamines and sterically bulky benzylamines from diaryl and sterically hindered ketones via asymmetric reductive amination reaction.
  • For the conversion of levulinic acid to optically active γ-valerolactone via asymmetric hydrogenation reaction.

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