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ChemicalBook >> CAS DataBase List >>(R)-C3-TUNEPHOS

(R)-C3-TUNEPHOS

CAS No.
486429-99-6
Chemical Name:
(R)-C3-TUNEPHOS
Synonyms
(R)-C3-TUNEPHOS;(S)-C3-TUNEPHOS;(S)-C3-TunePhos;(S)-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin;1,13-Bis(diphenylphosphanyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;1,13-bis(diphenylphosphaneyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;(R)-(6,6'-O-(1,3-PROPYLENE)-OXYLBIPHENYL-2,2'-DIYL)BIS(DIPHENYL)PHOSPHINE;(S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN;(S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN
CBNumber:
CB6139371
Molecular Formula:
C39H32O2P2
Molecular Weight:
594.62
MDL Number:
MFCD06658115
MOL File:
486429-99-6.mol
Last updated:2025-07-16 09:56:26

(R)-C3-TUNEPHOS Properties

Melting point 153-161 °C(lit.)
Boiling point 709.9±60.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
form Powder
color white
optical activity 240.867° (C=0.5 chloroform)
Sensitive air sensitive
UNSPSC Code 12352005

SAFETY

Risk and Safety Statements

WGK Germany  3

(R)-C3-TUNEPHOS price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-0176 (S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 95% (S)-C3-TUNEPHOS 486429-99-6 100mg $130 2024-03-01 Buy
Strem Chemicals 15-0176 (S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 95% (S)-C3-TUNEPHOS 486429-99-6 500mg $518 2024-03-01 Buy
American Custom Chemicals Corporation ING0001361 (S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN 95.00% 486429-99-6 1G $630 2021-12-16 Buy
Crysdot CD51000906 (S)-C3-TunePhos 95+% 486429-99-6 1g $1409 2021-12-16 Buy
Aaron Chemicals AR003DCB (S)-C3-TunePhos 98% 486429-99-6 250mg $233 2021-12-16 Buy
Product number Packaging Price Buy
15-0176 100mg $130 Buy
15-0176 500mg $518 Buy
ING0001361 1G $630 Buy
CD51000906 1g $1409 Buy
AR003DCB 250mg $233 Buy

(R)-C3-TUNEPHOS Chemical Properties,Uses,Production

Reaction

  1. New generation of chiral biaryl phosphine ligands with tunable dihedral angles. The ability to modify the dihedral angle allows for the fine tuning of the catalyst system and optimization of enantioselectivity.
  2. Ru-C3-TUNEPHOS complexes are used for asymmetric hydrogenation of β-ketoesters , enol acetates , cyclic β-amino acids , α-phthalimide ketones , and α-keto esters .
  3. Rh-catalyzed hydroformylation of cyclopropenes.
Reactions of 486429-99-6

Uses

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation

Reactant for:

  • Asymmetric hydrogenation of ketones with TunePhos/diamine/ruthenium complexes
  • Stereoselective preparation of arylalkyl esters via enantioselective hydrogenation of enol acetates

Precatalyst for:
  • Enantioselective iridium-catalyzed carbonyl allylation from alcohol or aldehyde by transfer hydrogenative coupling of allyl acetate

Catalyst for:
  • Enantioselective hydrogenation of a-keto esters to a-hydroxy esters using Ru-tunephos catalysts

(R)-C3-TUNEPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-C3-TUNEPHOS Suppliers

Global( 33)Suppliers
Supplier Tel Email Country ProdList Advantage
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD 		+86-13017695106 +86-13676922317 jiuyitime@fdachem.com China 7887 58
Shanghai Daken Advanced Materials Co.,Ltd 		+86-2158073036 info@dakenam.com China 12888 58
XINXIANG RUNYU MATERIAL CO., LTD. 		+86-13592593621; +8613592593621 sales@runvmat.com China 431 58
Aladdin Scientific 		tp@aladdinsci.com United States 57505 58
J & K SCIENTIFIC LTD. 18210857532; 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 021-021-61259108 18621169085 market03@meryer.com China 40228 62
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44733 61
Bide Pharmatech Ltd. 400-164-7117 13681763483 product02@bidepharm.com China 42446 60
Xinxiang Runyu Material Co., Ltd. 166-166-37336996 15690792173 chenxi.song@runvmat.com China 286 55
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51395 80

View Lastest Price from (R)-C3-TUNEPHOS manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(S)-C3-TUNEPHOS pictures 2025-08-02 (S)-C3-TUNEPHOS
486429-99-6
 US $0.00-0.00 / G 1G 98% 500G XINXIANG RUNYU MATERIAL CO., LTD.
(S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine pictures 2025-07-09 (S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine
486429-99-6
 US $2.00-5.00 / KG 0.1KG 99% g-kg-tons ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
  • (S)-C3-TUNEPHOS pictures
  • (S)-C3-TUNEPHOS
    486429-99-6
  • US $0.00-0.00 / G
  • 98%
  • XINXIANG RUNYU MATERIAL CO., LTD.
(S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 97% (S)-C3-TUNEPHOS (R)-C3-TUNEPHOS (R)-(6,6'-O-(1,3-PROPYLENE)-OXYLBIPHENYL-2,2'-DIYL)BIS(DIPHENYL)PHOSPHINE R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN (S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN (S)-C3-TUNEPHOS (S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin,95%(S)-C3-TUNEPHOS (S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN (S)-C3-TUNEPHOS (S)-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin Phosphine, 1,1'-[(13aS)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[1,1-diphenyl- 1,13-bis(diphenylphosphaneyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine (S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine 1,13-Bis(diphenylphosphanyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine (S)-C3-TunePhos 486429-99-6 C39H32O2P2 Privileged Ligands ChiralQuest Ligands Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis organophosphine ligand