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ChemicalBook >> CAS DataBase List >>Peri acid

Peri acid

CAS No.
82-75-7
Chemical Name:
Peri acid
Synonyms
8-AMINONAPHTHALENE-1-SULFONIC ACID;PERI ACID;1,8-AMINO ACID;Perigastric acid;Schollkopf's acid (VAN);8-SULFO-1-NAPHTHYLAMINE;1.8 Clevs Acid(Peri Acid);1-AMINO-8-SULFONAPHTHALENE;8-Naphthol-1-sulfonic acid;Peri acid ISO 9001:2015 REACH
CBNumber:
CB0680336
Molecular Formula:
C10H9NO3S
Molecular Weight:
223.25
MDL Number:
MFCD00035730
MOL File:
82-75-7.mol
Last updated:2025-07-04 15:02:50

Peri acid Properties

Melting point >350°C
Boiling point 220°C (rough estimate)
Density 1.3588 (rough estimate)
refractive index 1.6500 (estimate)
pka pK1: 5.03 (25°C)
form powder to crystal
color Light yellow to Brown
Water Solubility 0.2g/L(21 ºC)
Merck 14,6405
BRN 983230
InChI InChI=1S/C10H9NO3S/c11-8-5-1-3-7-4-2-6-9(10(7)8)15(12,13)14/h1-6H,11H2,(H,12,13,14)
InChIKey CYJJLCDCWVZEDZ-UHFFFAOYSA-N
SMILES C1(S(O)(=O)=O)=C2C(C=CC=C2N)=CC=C1
CAS DataBase Reference 82-75-7(CAS DataBase Reference)
FDA UNII 0D93Y3MXV4
EPA Substance Registry System 1-Naphthalenesulfonic acid, 8-amino- (82-75-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H335-H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  C
Risk Statements  34
Safety Statements  26-27-36-45
TSCA  Yes
HS Code  29214500
NFPA 704
0
1 0

Peri acid price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical A0350 8-Amino-1-naphthalenesulfonic Acid >98.0%(HPLC) 82-75-7 25g $27 2025-07-31 Buy
TCI Chemical A0350 8-Amino-1-naphthalenesulfonic Acid >98.0%(HPLC) 82-75-7 100g $71 2025-07-31 Buy
TCI Chemical A0350 8-Amino-1-naphthalenesulfonic Acid >98.0%(HPLC) 82-75-7 500g $119 2023-01-07 Buy
TRC A577168 8-Amino-1-naphthalenesulfonic Acid 82-75-7 1g $45 2021-12-16 Buy
Biosynth Carbosynth FA133267 8-Aminonaphthalene-1-sulfonic acid 82-75-7 500mg $60 2021-12-16 Buy
Product number Packaging Price Buy
A0350 25g $27 Buy
A0350 100g $71 Buy
A0350 500g $119 Buy
A577168 1g $45 Buy
FA133267 500mg $60 Buy

Peri acid Chemical Properties,Uses,Production

Chemical Properties

Dark green powder. 1-Aminonaphthalene-8-sulfonic acid [82- 75-7]. (8-aminonaphthalene-1-sulfonic acid), Peri acid, C10H9NO3S, Mr 223.24, crystallizes as the monohydrate and is sparingly soluble even in boiling water. The sodium salt is also sparingly soluble in water. Caustic fusion at 200℃ produces 8-amino-1- naphthol, whereas slow hydrolysis with 10 % sodium hydroxide at 220 – 260℃ yields 1,8- dihydroxynaphthalene. Sulfonation with cold 10 % oleum produces 1-aminonaphthalene-4,8- disulfonic acid, whereas hot concentrated sulfuric acid results in slow isomerization into naphthionic acid.

Uses

Intermediate of dyestuff. Dehydration with phosphorus oxychloride yields naphthosultam, and diazotization followed by hydrolysis results in naphthosultone, the intermediate for 1- hydroxynaphthalene-8-sulfonic acid. Diazotization followed by a Sandmeyer cyanide reaction gives 8-cyanonaphthalene-1-sulfonic acid, one of the most industrially important Sandmeyer reaction products because the nitrile forms the lactam, naphthostyril [130-00-7], upon treatment with concentrated alkali at 185℃. Hydrolysis of naphthostyril with dilute alkali yields 8-aminonaphthalene-1-carboxylic acid, which is the key intermediate for production of anthanthrone vat dyes via 1,10 -binaphthyl8,80 -dicarboxylic acid.

Production Methods

Naphthalene is converted to naphthalene-1-sulfonic acid. The crude sulfonation product is diluted with sulfuric acid, and 67.5 % nitric acid is added slowly at 30℃ to give the 5- and 8-nitro derivatives. The products are converted to the readily soluble magnesium salts by addition of a slurry of dolomite. The reaction mixture is neutralized with chalk and filtered hot. The filtrate is run into a suspension of iron powder in boiling water, which is kept slightly acidic with sulfuric acid. When reduction is complete, dissolved iron is precipitated by addition of magnesia, the iron residues are filtered off while hot, and the resulting liquor is acidified to pH 4.5 with sulfuric acid to give 99 % pure Peri acid in 48 % yield. The filtrates are further acidified to precipitate crude Laurent’s acid. This may be purified via its magnesium salt to give a 17 % yield of pure 1,5-isomer.

91-20-3
82-75-7
Synthesis of Peri acid from Naphthalene
Global( 328)Suppliers
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Hebei Chuanghai Biotechnology Co., Ltd
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View Lastest Price from Peri acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Peri acid pictures 2025-08-08 Peri acid
82-75-7
US $0.00 / G/KG 1G/KG 99% 100MT Anhuyan (Hainan) Biotechnology Co., LTD
Peri acid pictures 2025-08-08 Peri acid
82-75-7
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mujin Biotechnology Co.,Ltd
8-Amino-1-Naphthalenesulfonic Acid pictures 2025-07-02 8-Amino-1-Naphthalenesulfonic Acid
82-75-7
US $50.00 / mg 97.2% 10g TargetMol Chemicals Inc.
  • Peri acid pictures
  • Peri acid
    82-75-7
  • US $0.00 / G/KG
  • 99%
  • Anhuyan (Hainan) Biotechnology Co., LTD
  • Peri acid pictures
  • Peri acid
    82-75-7
  • US $0.00 / KG
  • 99%
  • Hebei Mujin Biotechnology Co.,Ltd
8-azanylnaphthalene-1-sulfonic acid 1,8-Naphthylaminesulfonic acid 1-Aminonaphthalene-8-sulfonic acid NAPHTHYLAMINOMONOSULFONIC ACID PERI ACID 1-Amino-8-naphthalenesulfonic Acid 1-Naphthylamine-8-sulfonic Acid Peri Acid 1.8 Clevs Acid(Peri Acid) 1-Amino-8-naphthalene sulfonate 1-Aminonaphthalene-8-sulfonate Naphthylaminemonosulfonic acid S Schollkopf's acid (VAN) 8-amino-1-naphthalenesulfonicaci 8-Naphthylamine-1-sulfonicacid 1,8-AMINO ACID 1-AMINO-8-NAPHTHALENESULFONIC ACID 1-AMINO-8-SULFONAPHTHALENE 8-AMino-1-naphthalenesulfonic acid, 98%, 98% 1-NAPHTHYLAMINE-8-SULFONIC ACID 8-AMINO-1-NAPHTHALENESULFONIC ACID 8-AMINONAPHTHALENE-1-SULPHONIC ACID 8-SULFO-1-NAPHTHYLAMINE ALPHA-NAPHTHYLAMINE-8-SULFONIC ACID 1-Amino-8-naphtalenesulfonic acid 1-Naphthylamine-8-sulphonic acid 8-amino-1-naphthalenesulfonic acid (peri acid) 1-Naphthalenesulfonic acid, 8-amino- 8-Naphthol-1-sulfonic acid 8-Amino-1-naphthalenesulfonicAcid> Peri acid ISO 9001:2015 REACH 8-AMINONAPHTHALENE-1-SULFONIC ACID Peri acid/8-Amino-1-naphthalenesulfonic acid Perigastric acid 82-75-7 Intermediates of Dyes and Pigments bc0001