| Identification | Back Directory | [Name]
N-(4-biphenyl)-(9,9-dimethylfluoren-2--yl)Amine | [CAS]
897671-69-1 | [Synonyms]
BADMF
DMFNB
N-(4-biphenyl)-(9
9-dimethylfluoren-2--yl)Amine
9,9-diMethyl-N-(4-phenylphenyl)-9H-fluore
2-(4-Biphenylyl)amino-9,9-dimethylfluorene
2-(4-Biphenylyl)amino-9,9-dimethylfluorene >
N-(4-biphenyl)-(9,9-diMethylfluorene-2-yl)AMine
N-(4-biphenyl)-(9,9-dimethylfluoren-2--yl)Amine
N-(bipheny-4-yl)-9,9-diMethyl-9H-fluoren-2-aMine
N-(biphenyl-4-yl)-9,9-diMethyl-9H-fluoren-2-aMine
N-(bipheny-4-y1)-9,9-dimethyl1-9H-fluoren-2-amine
2-(4-Biphenylyl)amino-9,9-dimethylfluorene, 99.5%
9,9-diMethyl-N-(4-phenylphenyl)-9H-fluoren-2-aMine
N-(4-biphenyl)-(9,9-diMethylfluoren-2-yl)AMine
99%
N-[1,1'-Biphenyl]-4-yl-9,9-dimethyl-9H-fluoren-2-amine
9H-Fluoren-2-amine, N-[1,1'-biphenyl]-4-yl-9,9-dimethyl
N-([1,1'-biphenyl]-4-yl)-9,9-dimethyl-9H-fluoen-2-amine
9H-Fluoren-2-amine, N-[I,1'-biphenyI]4-yl-9,9-dimethyI-
N-(Biphenyl-4-yl)-9,9-dimethyl-9H-fluoren-2-amine 897671-69-1
N-[1,1'-Biphenyl]-4-yl-9,9-dimethyl-9H-fluoren-2-amineN-[1,1'-
N-(4-biphenyl)-(9,9-dimethylfluoren-2--yl)Amine ISO 9001：2015 REACH | [EINECS(EC#)]
807-964-9 | [Molecular Formula]
C27H23N | [MDL Number]
MFCD16036286 | [MOL File]
897671-69-1.mol | [Molecular Weight]
361.478 |
| Chemical Properties | Back Directory | [Melting point ]
145.0 to 149.0 °C | [Boiling point ]
539.6±39.0 °C(Predicted) | [density ]
1.136 | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly) | [form ]
Solid | [pka]
0.90±0.40(Predicted) | [color ]
White to Off-White | [InChI]
InChI=1S/C27H23N/c1-27(2)25-11-7-6-10-23(25)24-17-16-22(18-26(24)27)28-21-14-12-20(13-15-21)19-8-4-3-5-9-19/h3-18,28H,1-2H3 | [InChIKey]
QRMLAMCEPKEKHS-UHFFFAOYSA-N | [SMILES]
C1(C)(C)C2=C(C=CC=C2)C2=C1C=C(NC1=CC=C(C3=CC=CC=C3)C=C1)C=C2 | [CAS DataBase Reference]
897671-69-1 |
| Hazard Information | Back Directory | [Chemical Properties]
white powder | [Uses]
N-([1,1''-Biphenyl]-4-yl)-9,9-dimethyl-9H-fluoren-2-amine (cas# 897671-69-1) is a useful compound for preparing amine-containing organic compounds. | [Synthesis]
The general procedure for the synthesis of N-([1,1'-biphenyl]-4-yl)-9,9-dimethyl-9H-fluoren-2-amine from 9,9-dimethyl-2-bromofluorene and 4-amino biphenyl was as follows: in a reactor 50.0 g (330 mmol) of 4-amino biphenyl, 43.2 g (276 mmol) of 2-bromo-9,9-dimethyl-9H-fluorene, 1.2 g (5.6 mmol) palladium acetate, 6.4 g (11.02 mmol) phosphine ligand, and 126 g (386 mmol) cesium carbonate were dissolved in 1000 mL of toluene. The reaction mixture was stirred under reflux conditions for 24 hours. After completion of the reaction, it was cooled to room temperature, the reaction mixture was filtered and the filtrate was concentrated under reduced pressure. Purification by column chromatography afforded 57 g of the target product in 91% yield. | [References]
[1] Patent: KR2015/130797, 2015, A. Location in patent: Paragraph 0453-0458
[2] Patent: KR2015/114636, 2015, A. Location in patent: Paragraph 0546-0551
[3] Patent: CN107686484, 2018, A. Location in patent: Paragraph 0085-0088
[4] Patent: KR2016/78765, 2016, A. Location in patent: Paragraph 0187; 0190; 0195; 0196
[5] Patent: US2017/125688, 2017, A1. Location in patent: Paragraph 0314-0316 |
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