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ChemicalBook--->CAS DataBase List--->84086-96-4

84086-96-4

84086-96-4 Structure

84086-96-4 Structure
IdentificationBack Directory
[Name]

3,7-dichloro-8-chloro methyl quinoline
[CAS]

84086-96-4
[Synonyms]

3,7,8-trichloro-2-methylquinoline
3,7-dichloro-8-chloro methyl quinoline
Quinoline, 3,7-dichloro-8-(chloromethyl)-
[Molecular Formula]

C10H6Cl3N
[MDL Number]

MFCD19707337
[MOL File]

84086-96-4.mol
[Molecular Weight]

246.52
Chemical PropertiesBack Directory
[Boiling point ]

348.3±37.0 °C(Predicted)
[density ]

1.464±0.06 g/cm3(Predicted)
[pka]

0.04±0.42(Predicted)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

1,2-Dichlorobenzene-->BUTYRONITRILE-->3,7-dichloro-8-dichloro methyl quinoline-->7-CHLORO-8-METHYLQUINOLINE
[Preparation Products]

3,7-dichloro-8-dichloro methyl quinoline-->Quinclorac
Hazard InformationBack Directory
[Chemical Properties]

3,7-dichloro-8-chloro methyl quinoline is pure white crystal, mp129℃, soluble in organic solvents such as ethanol, benzene, chlorobenzene, dichlorobenzene, slightly soluble in petroleum ether, insoluble in water.
[Uses]

3,7-Dichloro-8-chloromethylquinoline is an intermediate of the herbicide quinclorac.
[Synthesis]

3,7-dichloro-8-chloro methyl quinoline's preparation method is to put 7-chloro-8-methylquinoline and o-dichlorobenzene in the reactor, and add catalyst azobisisobutyronitrile, heat up, pass chlorine gas, and control unreacted quinoline with gas chromatography, The content is less than or equal to 1%. Precipitation and recovery of o-dichlorobenzene give a mixture of 3,7-dichloro-8-chloromethylquinoline.
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