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ChemicalBook--->CAS DataBase List--->70749-06-3

70749-06-3

70749-06-3 Structure

70749-06-3 Structure
IdentificationBack Directory
[Name]

(1S,2S)-(-)-N,N'-DIMETHYL-1,2-DIPHENYL-1,2-ETHANE DIAMINE
[CAS]

70749-06-3
[Synonyms]

(1S,2S)-(-)-N,N'-DIMETHYL-1,2-DIPHENYLETHYLENEDIAMINE
(1S,2S)-N1,N2-dimethyl-1,2-diphenylethane-1,2-diamine
(1S,2S)-N,N'-Dimethyl-1,2-diphenyl-1,2-ethylenediamine
(1S,2S)-(-)-N,N'-DIMETHYL-1,2-DIPHENYL-1,2-ETHANE DIAMINE
(1S,2S)-(-)-N,N'-Dimethyl-1,2-diphenyl-1,2-ethane diamine,99%
[Molecular Formula]

C16H20N2
[MDL Number]

MFCD00216956
[MOL File]

70749-06-3.mol
[Molecular Weight]

240.34
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystals or cryst. powder
[Melting point ]

48-51 °C
[Boiling point ]

373.06°C (rough estimate)
[density ]

1.0485 (rough estimate)
[refractive index ]

1.5519 (estimate)
[Fp ]

110℃
[storage temp. ]

Keep in dark place,Inert atmosphere,2-8°C
[form ]

Crystals or Crystalline Powder
[pka]

9.14±0.30(Predicted)
[color ]

White to light yellow
[Optical Rotation]

[α]22/D -17.0°, c =0.5 in chloroform
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystals or cryst. powder
[Uses]

(1S,2S)-N,N′-Dimethyl-1,2-diphenyl-1,2-ethylenediamine can be used as:
  • A precursor for the synthesis of chiral imidazolinium salts, which are used as catalysts for aza Diels?Alder reaction and as shift reagents for potassium salt of Mosher′s acid.
  • A ligand in the preparation of 2,3-dihydrobenzofurans and indanes by reacting alkyl halides with alkyl electrophiles using nickel/diamine catalyst.
  • A ligand in the synthesis of carbamates, sulfonamides, and sulfones through alkyl-alkyl Suzuki reaction using Ni catalyst.

Safety DataBack Directory
[Hazard Codes ]

C,N,Xn
[Risk Statements ]

34-50-22
[Safety Statements ]

45-36/37/39-26-61
[HS Code ]

29215990
Spectrum DetailBack Directory
[Spectrum Detail]

(1S,2S)-(-)-N,N'-DIMETHYL-1,2-DIPHENYL-1,2-ETHANE DIAMINE(70749-06-3)1HNMR
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