| Identification | Back Directory | [Name]
3',5'-diphenylbiphenyl-4-aMine | [CAS]
343239-58-7 | [Synonyms]
3,,5,-diphenylbipheny-4-amine
5'-Phenyl-m-terphenyl-4-amine
3',5'-diphenylbiphenyl-4-aMine
4-AMino-3',5'-diphenylbiphenyl, 98%
5'-Phenyl-[1,1':3',1''-terphenyl]-4-aMine
[1,1':3',1''-Terphenyl]-4-amine, 5'-phenyl-
[1,1':3',1''-Terphenyl]-4-amine, 5'-phenyl- (9CI) | [Molecular Formula]
C24H19N | [MOL File]
343239-58-7.mol | [Molecular Weight]
321.414 |
| Chemical Properties | Back Directory | [Melting point ]
138-139℃ | [Boiling point ]
505℃ | [density ]
1.117 | [Fp ]
275℃ | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [form ]
powder to crystal | [pka]
4.24±0.10(Predicted) | [color ]
White to Gray to Brown |
| Hazard Information | Back Directory | [Synthesis]
In a 500 mL autoclave, 200 mL of ethanol, 3.51 g (0.01 mol) of 4-nitro-5'-phenyl-1,1':3',1''-biphenyl, and 0.4 g of 5% Pd/C catalyst were added. The reaction temperature was controlled to be 60 °C and the catalytic hydrogenation reaction was carried out under 0.2 MPa hydrogen pressure. After the reaction was completed, it was cooled to room temperature and the gas in the reactor was replaced with nitrogen. The reaction solution was filtered to remove the catalyst and subsequently the filtrate was concentrated to dryness. The crude product was recrystallized using a mixed solvent of ethyl acetate and toluene to afford 3.06 g of 5'-phenyl-[1,1':3',1''-biphenyl]-4-amine in 95.33% yield. | [References]
[1] Patent: CN108164387, 2018, A. Location in patent: Paragraph 0083; 0101; 0102; 0103
[2] Patent: CN108191600, 2018, A. Location in patent: Paragraph 0055; 0073; 0074; 0075
[3] Chemical Physics Letters, 2001, vol. 337, # 1-3, p. 11 - 17 |
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