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ChemicalBook--->CAS DataBase List--->207399-11-9

207399-11-9

207399-11-9 Structure

207399-11-9 Structure
IdentificationBack Directory
[Name]

IRIDIUM(IV) CHLORIDE
[CAS]

207399-11-9
[Synonyms]

IRIDIUM CHLORIDE
etrachloroiridium,hydrate
tetrachloroiridium,hydrate
Iridium(Ⅳ)Chloride Hydrate
Iridium(IV) chloride hydrate technical grade
Iridium(IV) chloride hydrate, 99.9+% metals basis
Iridium(IV) chloride hydrate >=99.9% trace metals basis
[EINECS(EC#)]

625-260-8
[Molecular Formula]

Cl4Ir
[MDL Number]

MFCD00016155
[MOL File]

207399-11-9.mol
[Molecular Weight]

334.03
Chemical PropertiesBack Directory
[Melting point ]

>350 °C(lit.)
[form ]

crystalline
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

22-36/37/38
[Safety Statements ]

26-36/37
[WGK Germany ]

3
[RTECS ]

NO3610000
Hazard InformationBack Directory
[Uses]

Iridium(IV) chloride hydrate can be used:
  • To fabricate an Ir-decorated graphene electrode for vanadium redox flow batteries.
  • As a precursor to synthesize iridium oxide nanoparticles. These nanoparticles can act as a stable catalyst for the hydrogenation of a series of nitrogen heterocycles.
  • To prepare Ir single atom catalyst (Ir1–Ni(OH)2) for oxygen evolution reaction.
[reaction suitability]

reagent type: catalyst
core: iridium
[Purification Methods]

If it contains nitrogen, then repeatedly concentrate a conc HCl solution until free from nitrogen, and dry free from HCl in a vacuum over CaO until crystals are formed. The olive-green solid (yellow at ~700o) is very hygroscopic. [Woo & Yost J Am Chem Soc 53 884 1931, Grube in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p1592 1965.]
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