| Identification | Back Directory | [Name]
3-ETHOXY-3-OXOPROPYLZINC BROMIDE | [CAS]
193065-68-8 | [Synonyms]
zinc bromide soL
3-Ethoxy-3-oxopropyL
3-ETHOXY-3-OXOPROPYLZINC BROMIDE
2-(Ethoxycarbonyl)ethylzinc bromide
(3-ethoxy-3-oxopropyl)zinc(II) broMide
3-ethoxy-3-oxopropylzinc bromide solution
2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF
3-Ethoxy-3-oxopropylzinc bromide solution 0.5 in THF
3-Ethoxy-3-oxopropylzinc broMide solution 0.5 M in THF
3-ETHOXY-3-OXOPROPYLZINC BROMIDE, 0.5MSO LUTION IN TETRAHYDROFURAN | [Molecular Formula]
C5H9BrO2Zn | [MDL Number]
MFCD00671976 | [MOL File]
193065-68-8.mol | [Molecular Weight]
246.42 |
| Chemical Properties | Back Directory | [density ]
0.972 g/mL at 25 °C
| [Fp ]
1 °F
| [storage temp. ]
2-8°C | [Water Solubility ]
Reacts with water. | [Exposure limits]
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) |
| Hazard Information | Back Directory | [Uses]
3-Ethoxy-3-oxopropylzinc bromide is a reagent used to insert ethyl propanoate group to the substrate. It can be used in:
- Synthesis of γ-keto esters from aryl chlorides.
- Synthesis of sulfones from 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) (DABSO) and alkyl halides.
- Negishi cross-couplings with aryl vinyl phosphates to synthesize 1,1-disubstituted alkenes.
|
|
| Company Name: |
Alfa Aesar
|
| Tel: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Infinity SCI
|
| Tel: |
400-400-1062016 17800804092 |
| Website: |
http://www.infsci.com |
|