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ChemicalBook--->CAS DataBase List--->15051-46-4

15051-46-4

15051-46-4 Structure

15051-46-4 Structure
IdentificationBack Directory
[Name]

TEMPO Methacrylate
[CAS]

15051-46-4
[Synonyms]

PTMA Monomer
TEMPO Methacrylate
TEMPO methacrylate 98%
4-Methacryloyloxy-TEMPO Free Radical
4-Methacryloyloxy-2,2,6,6-tetramethylpiperidine1-OxylFreeRadical>
4-Methacryloyloxy-2,2,6,6-tetraMethylpiperidine 1-Oxyl Free Radical
2,2,6,6-Tetramethyl-4-[(2-methyl-1-oxo-2-propenyl)oxy]-1-piperidinyloxy
[Molecular Formula]

C13H24NO3 *
[MDL Number]

MFCD17677357
[MOL File]

15051-46-4.mol
[Molecular Weight]

242.335
Chemical PropertiesBack Directory
[Melting point ]

87.0 to 91.0 °C
[storage temp. ]

2-8°C
[form ]

powder to crystal
[color ]

Light yellow to Yellow to Orange
[InChI]

InChI=1S/C9H18NO.C4H6O2/c1-8(2)6-5-7-9(3,4)10(8)11;1-3(2)4(5)6/h5-7H2,1-4H3;1H2,2H3,(H,5,6)
[InChIKey]

PQWUKJSMPXZYSL-UHFFFAOYSA-N
[SMILES]

C1CC(C)(C)N([O])C(C)(C)C1.C(O)(=O)C(=C)C |^1:6|
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

43
[Safety Statements ]

36/37
[WGK Germany ]

1
[HS Code ]

29333990
Hazard InformationBack Directory
[Chemical Properties]

White to orange powder
[Uses]

2,2,6,6-Tetramethyl-4-[(2-methyl-1-oxo-2-propenyl)oxy]-1-piperidinyloxy is used in the synthesis of Poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate). Poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) has application in batteries and solar cells.
[Uses]

TEMPO methacrylate (4-Methacryloyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl) may be employed as counter radical for polymerization of styrene.
[Definition]

ChEBI: 4-methacryloyloxy-TEMPO is a member of the class of piperidines that is TEMPO carrying a methacryloyloxy group at position 4. It has a role as a polymerisation monomer. It is a member of aminoxyls, a member of piperidines and an enoate ester. It is functionally related to a TEMPO.
[General Description]

TEMPO methacrylate (4-Methacryloyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl) undergoes anionic dispersion polymerization to afford nanometer-sized polymer particles bearing 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) radicals.
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